{"id":"W4248918541","doi":"10.14293/s2199-1006.1.sop-chem.a7jmrd.v1","title":"Diazonium Salts as Grafting Agents and Efficient Radical Hydrosilylation Initiators for Freestanding Photoluminescent Silicon Nanocrystals","year":2014,"lang":"en","type":"article","venue":"ScienceOpen Posters","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Hydrosilylation; Grafting; Nanocrystal; Photoluminescence; Materials science; Silicon; Polymer chemistry; Photochemistry; Chemistry; Chemical engineering; Nanotechnology; Organic chemistry; Catalysis; Optoelectronics; Composite material; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002459126,0.0003550698,0.000159302,0.000175394,0.00009461543,0.0002158167,0.0002202247,0.0003031196,0.0004602254],"category_scores_gemma":[0.0001935061,0.0002231158,0.0001843462,0.00008175053,0.0001995586,0.0002722208,0.000197587,0.0003325871,0.0002605327],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002768351,"about_ca_system_score_gemma":0.0001308181,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001780079,"about_ca_topic_score_gemma":0.0006176582,"domain_scores_codex":[0.9998828,0.00001805199,0.00001321313,0.00002647077,0.00004328965,0.00001613012],"domain_scores_gemma":[0.9999083,0.0000273752,0.00002713721,0.00000891029,0.00001468003,0.00001351244],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001759439,0.000005700894,0.00002637646,0.00002775524,0.000002209068,0.00002351701,0.000008314948,0.00004443455,0.9989637,0.00008701024,0.00001460468,0.0007786828],"study_design_scores_gemma":[0.000004662065,0.00003866243,0.00009797817,0.000001596815,0.00000346166,0.00002920117,0.000002285453,0.0001728446,0.9990988,0.000009919254,0.000539111,0.000001635216],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863711,0.002815573,0.008058214,0.0001132473,0.00004663651,0.00005541478,0.0001196162,0.000083763,0.002336401],"genre_scores_gemma":[0.9865702,0.001890367,0.008747126,0.00005038488,0.0000188742,0.00003631285,0.0001334223,0.00003922703,0.002514092],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004602254,"threshold_uncertainty_score":0.002008557,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01384995784021278,"score_gpt":0.263083561442734,"score_spread":0.2492336036025212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}