{"id":"W4249050149","doi":"10.1139/cjc-78-9-1194","title":"Reaction of dimetho×ycarbene with strained cyclic carbonyl compounds","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Computational chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001233193,0.0001982084,0.0003503161,0.00007312849,0.00006979069,0.00002843098,0.0002719067,0.000183686,0.004832845],"category_scores_gemma":[0.00004051869,0.0001887501,0.0001374531,0.0001700156,0.000100391,0.0001192445,0.000004188285,0.0004729748,0.000004244092],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003926397,"about_ca_system_score_gemma":0.001169062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001779663,"about_ca_topic_score_gemma":0.00110349,"domain_scores_codex":[0.9987192,0.0000121015,0.0004882745,0.0001698082,0.0003059374,0.0003046528],"domain_scores_gemma":[0.9983587,0.00003861792,0.0004117907,0.0003177141,0.000240774,0.0006324316],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008269468,0.00001962702,0.0003924603,0.000168587,0.00008873021,0.0001527489,0.0002660552,0.00005204688,0.9850019,0.000005605022,0.00009869238,0.01367091],"study_design_scores_gemma":[0.0009010878,0.00004228205,0.0005602001,0.0001840142,0.00008215119,0.001632042,0.0009062917,0.000008922812,0.9855075,0.0001011697,0.009858346,0.0002159563],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.891957,0.000323125,0.00001389077,0.00008812755,0.00005451143,0.00002460965,0.00003515289,0.00001295005,0.1074907],"genre_scores_gemma":[0.9971582,0.00003481243,0.0004848554,0.00001987636,0.0003092219,0.000001607339,0.00001776354,0.00003716315,0.001936525],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1055541,"threshold_uncertainty_score":0.9960769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007682582055841707,"score_gpt":0.2007384648551241,"score_spread":0.1930558827992824,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}