{"id":"W4249344561","doi":"10.1002/ange.201611196","title":"Trapping Rare and Elusive Phosphinidene Chalcogenides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphinidene; Chemistry; Reactivity (psychology); Selenide; Monomer; Sulfide; Trapping; Carbene; Organometallic chemistry; Graphene; Photochemistry; Nanotechnology; Organic chemistry; Materials science; Catalysis; Polymer; Selenium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001274219,0.000220841,0.0001625455,0.0001567043,0.0001707438,0.0003865215,0.0003077193,0.0002221538,0.001399891],"category_scores_gemma":[0.0001282749,0.0001085666,0.00008866126,0.00011946,0.0003023378,0.0002627519,0.0003990242,0.0002703585,0.0003333446],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003208328,"about_ca_system_score_gemma":0.0002240518,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00029686,"about_ca_topic_score_gemma":0.0006699548,"domain_scores_codex":[0.999916,0.00001203493,0.000004486528,0.00001778392,0.00002468546,0.00002497847],"domain_scores_gemma":[0.9999365,0.00001178391,0.00001967358,0.00001055293,0.000009717976,0.0000117526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008840548,0.00001725647,0.0001739356,0.0001158312,0.00000884616,0.0002120788,0.00007175179,0.0004562677,0.9927629,0.002524639,0.0001903349,0.003377805],"study_design_scores_gemma":[0.00001324527,0.0001041275,0.0002079486,0.000002769187,0.000005139631,0.00008568976,0.00001773518,0.0007721856,0.9966434,0.0001333907,0.002009628,0.000004918129],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986161,0.001040095,0.004848188,0.0001194018,0.00003145341,0.00002592501,0.0001601247,0.0001180558,0.007495758],"genre_scores_gemma":[0.9952526,0.0003146992,0.001992921,0.00001815209,0.00000520876,0.0000104877,0.0000612265,0.00001308022,0.00233158],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001399891,"threshold_uncertainty_score":0.004683137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02608628022460252,"score_gpt":0.2467840179405126,"score_spread":0.22069773771591,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}