{"id":"W4249576900","doi":"10.1002/ange.201804277","title":"Diastereocontrolled Monoprotodeboronation of β‐Sulfinimido <i>gem</i>‐Bis(boronates): A General and Stereoselective Route to α,β‐Disubstituted β‐Aminoalkylboronates","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Stereocenter; Chemistry; Stereoselectivity; Geminal; Alkyl; Enantiomer; Aryl; Stereochemistry; Aldimine; Bond cleavage; Medicinal chemistry; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002277574,0.0005465918,0.0001927552,0.0002299115,0.0001573407,0.0002115484,0.0003043166,0.0002164708,0.001527939],"category_scores_gemma":[0.0001234248,0.0002278601,0.0001559813,0.0001409968,0.0002120705,0.0003284596,0.0002986438,0.0003705473,0.000608516],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002854768,"about_ca_system_score_gemma":0.0003426905,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005640929,"about_ca_topic_score_gemma":0.001246608,"domain_scores_codex":[0.9998589,0.00002893964,0.00001061424,0.00002309312,0.00002088523,0.00005759287],"domain_scores_gemma":[0.9999408,0.0000061675,0.00001830864,0.000006525539,0.000008600906,0.00001965774],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001333059,0.00002151199,0.00007119279,0.0001009065,0.000007526973,0.00008641613,0.00005024023,0.0001378507,0.9957372,0.001000665,0.0001398816,0.002513362],"study_design_scores_gemma":[0.00002072424,0.0001663518,0.0002485611,0.000005677462,0.000006248033,0.0001050684,0.00001250954,0.0002904793,0.9965708,0.0000813506,0.002484905,0.000007302837],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9639643,0.001955876,0.01658198,0.0002082633,0.0001249452,0.0001175845,0.0004901316,0.0004345314,0.01612253],"genre_scores_gemma":[0.9918209,0.0009924712,0.00461618,0.00005517693,0.00001028167,0.00002615636,0.0002012985,0.00005433226,0.002223192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001527939,"threshold_uncertainty_score":0.005111456,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01062832258345356,"score_gpt":0.2422671693727615,"score_spread":0.2316388467893079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}