{"id":"W4249812535","doi":"10.26434/chemrxiv.14054783","title":"N-Ammonium Ylide Mediators for Selective Electrochemical C–H Oxidation","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; Nadace Experientia; Japan Society for the Promotion of Science; Natural Sciences and Engineering Research Council of Canada; National Institutes of Health; National Science Foundation","keywords":"Chemistry; Reagent; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003958546,0.0005120975,0.0002399207,0.0001871159,0.000215366,0.0003298425,0.0006530629,0.0005111273,0.004702278],"category_scores_gemma":[0.0004932908,0.0002322991,0.0001783269,0.0001629619,0.0002459677,0.0007947804,0.0006141025,0.001056905,0.001724668],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004190305,"about_ca_system_score_gemma":0.0003462797,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000379909,"about_ca_topic_score_gemma":0.001261381,"domain_scores_codex":[0.9997298,0.00003836024,0.00002373873,0.0000688368,0.00008377289,0.00005551151],"domain_scores_gemma":[0.999912,0.00002296803,0.0000237364,0.00001157061,0.00001853292,0.00001120175],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001630309,0.0001284878,0.0001698323,0.0007385275,0.00002721858,0.0003531304,0.0001221545,0.0008662865,0.9527041,0.01229176,0.005847602,0.02658792],"study_design_scores_gemma":[0.00002563611,0.0002867311,0.0001531463,0.00002174748,0.000009101977,0.0001930703,0.00003876692,0.002615302,0.9700874,0.0005795466,0.02597181,0.00001756476],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.5906716,0.01640654,0.2609741,0.004479636,0.00256129,0.0008334734,0.002109299,0.003216794,0.1187471],"genre_scores_gemma":[0.9450197,0.006267368,0.03085306,0.0007100328,0.0001463154,0.0002634758,0.0006014677,0.0001289407,0.01600967],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.004702278,"threshold_uncertainty_score":0.01573068,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01939313740728237,"score_gpt":0.294029789232576,"score_spread":0.2746366518252936,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}