{"id":"W4250039782","doi":"10.1002/ange.201307410","title":"Highly Stereoselective Recognition and Deracemization of Amino Acids by Supramolecular Self‐Assembly","year":2013,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Stereoselectivity; Amino acid; Supramolecular chemistry; Chemistry; Aldehyde; Salt (chemistry); Stereochemistry; Guanidine; Chirality (physics); Combinatorial chemistry; Organic chemistry; Crystal structure; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001308545,0.0002320242,0.0001755334,0.0001532153,0.0001268899,0.0002472029,0.0002289937,0.0001615629,0.001155543],"category_scores_gemma":[0.0001514154,0.000141439,0.0001262821,0.0001021685,0.0001763405,0.0001820138,0.0002686452,0.0003105015,0.0004944993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002193188,"about_ca_system_score_gemma":0.0001241945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003152502,"about_ca_topic_score_gemma":0.0006480088,"domain_scores_codex":[0.999895,0.00001097297,0.000007676273,0.0000263781,0.00003024486,0.00002976153],"domain_scores_gemma":[0.9999337,0.00001102941,0.00001707664,0.000009319725,0.00001338209,0.00001556003],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002299617,0.00001166356,0.00005180246,0.00002140059,0.000003082539,0.00002376283,0.00001252604,0.0001633414,0.9975992,0.0002376361,0.00007055508,0.00178214],"study_design_scores_gemma":[0.000008321798,0.00004648783,0.0002190208,0.000001060056,0.000002232329,0.0000277052,0.000005222136,0.002029664,0.9967308,0.00003519119,0.0008904124,0.00000383147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9841008,0.000576596,0.009237931,0.0001056637,0.00005579785,0.00003641207,0.0001110145,0.0003167009,0.005458984],"genre_scores_gemma":[0.9962746,0.0001036804,0.002455187,0.00002781862,0.000006126029,0.0000101477,0.00003865085,0.00001555328,0.001068227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001155543,"threshold_uncertainty_score":0.003865719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009301624816264193,"score_gpt":0.2017444250357772,"score_spread":0.192442800219513,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}