{"id":"W4251229383","doi":"10.26434/chemrxiv.14157059","title":"Acylboronates in Polarity-Reversed Generation of Acyl Palladium(II) Intermediates","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Palladium; Chemistry; Halide; Aryl; Polarity (international relations); Boron; Medicinal chemistry; Catalysis; Mass spectrometry; Ion; Reactivity (psychology); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002166498,0.0004618339,0.0001842499,0.0002060457,0.0001680487,0.0003436499,0.0004371144,0.0003672309,0.002129657],"category_scores_gemma":[0.000184353,0.0001925469,0.0001779515,0.0001836094,0.0002924303,0.0004034381,0.0005671873,0.0006158762,0.0008748185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002283677,"about_ca_system_score_gemma":0.0002019736,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005039364,"about_ca_topic_score_gemma":0.0008688378,"domain_scores_codex":[0.9998242,0.000029542,0.00001310215,0.00003433049,0.00004619651,0.00005261703],"domain_scores_gemma":[0.999941,0.00000990117,0.00001524244,0.000009602869,0.00001023864,0.00001397027],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001317704,0.0000355098,0.0001256847,0.000182491,0.00001629125,0.0002946334,0.0001517237,0.0003513997,0.989926,0.003132685,0.0002469257,0.005404853],"study_design_scores_gemma":[0.00001750191,0.0001223826,0.0001094514,0.000003197668,0.000009563986,0.00012107,0.00001872981,0.0003328256,0.995821,0.0001983015,0.003237739,0.000008189926],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9514427,0.002717808,0.02676255,0.0003784498,0.0001673094,0.000125486,0.000430817,0.0004241604,0.01755072],"genre_scores_gemma":[0.9904136,0.001355577,0.004468098,0.00007136239,0.00001449652,0.0000287598,0.0001989726,0.0000471182,0.00340194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002129657,"threshold_uncertainty_score":0.007124364,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02339746066753433,"score_gpt":0.2511891726369042,"score_spread":0.2277917119693698,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}