{"id":"W4251241439","doi":"10.1002/ange.201509130","title":"Regioselective Synthesis of Nanographenes by Photochemical Cyclodehydrochlorination","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Graphene research and applications","field":"Materials Science","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Regioselectivity; Photochemistry; Conjugated system; Steric effects; Molecule; Thiophene; Acetone; Benzene; Reaction mechanism; Pyridine; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002438994,0.00009953661,0.0001574327,0.00005716537,0.00004917768,0.00002029598,0.0002318505,0.00006355039,0.00005988167],"category_scores_gemma":[0.0002312357,0.00008923213,0.00006015998,0.0003530982,0.0001625063,0.0001212584,0.00004585675,0.00005558415,0.0000306023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003782954,"about_ca_system_score_gemma":0.00006341089,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008659665,"about_ca_topic_score_gemma":0.000004984905,"domain_scores_codex":[0.999031,0.00002358384,0.0001646366,0.0002288728,0.0003208439,0.0002310574],"domain_scores_gemma":[0.9992059,0.0001030444,0.00008381323,0.0002296937,0.000211889,0.0001657009],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003100158,0.00007994229,0.0002046971,0.00001221094,0.000007789082,3.707769e-7,0.00008173159,6.588621e-7,0.9823299,0.0001824658,0.01691516,0.000154042],"study_design_scores_gemma":[0.0001818341,0.00002539988,0.00005921851,0.00001469286,0.00001161982,0.000002554467,0.0001074399,0.000004557044,0.9936475,0.002546526,0.003301414,0.00009729064],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991629,0.0003841244,0.000254901,0.0002918095,0.00002823575,0.0001825077,0.00007272048,0.00006262936,0.007094046],"genre_scores_gemma":[0.9988579,0.00005809757,0.0006554069,0.00002114921,0.00003771824,0.0002119894,0.00001670081,0.00001098422,0.0001300945],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01361375,"threshold_uncertainty_score":0.3638781,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02456671398656571,"score_gpt":0.271541793059811,"score_spread":0.2469750790732453,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}