{"id":"W4251241439","doi":"10.1002/ange.201509130","title":"Regioselective Synthesis of Nanographenes by Photochemical Cyclodehydrochlorination","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Graphene research and applications","field":"Materials Science","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Regioselectivity; Photochemistry; Conjugated system; Steric effects; Molecule; Thiophene; Acetone; Benzene; Reaction mechanism; Pyridine; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007806606,0.000304568,0.0001148026,0.0002153991,0.00009624255,0.0001604364,0.0001710727,0.0001954647,0.00104598],"category_scores_gemma":[0.0001062371,0.0001113092,0.0001731877,0.0001697427,0.0001250663,0.0001879002,0.0001356986,0.0002562829,0.0002208225],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002806147,"about_ca_system_score_gemma":0.0002187156,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005479651,"about_ca_topic_score_gemma":0.001454073,"domain_scores_codex":[0.9999163,0.000008533617,0.000005368726,0.00002255204,0.00002106667,0.00002616232],"domain_scores_gemma":[0.9999171,0.00002077797,0.00002121773,0.00001513792,0.00001365598,0.00001198383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002010885,0.000009313256,0.00007236999,0.00004577024,0.000003566765,0.00004849979,0.00001412678,0.0001052043,0.9975677,0.0002286246,0.00004218982,0.001842648],"study_design_scores_gemma":[0.00000337694,0.00005333464,0.0004136279,0.000001787875,0.000004282615,0.00005177649,0.000004546324,0.0001220702,0.9975016,0.00002190221,0.001819184,0.0000025978],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9832534,0.001625625,0.00898211,0.00007679245,0.00004226061,0.0000600267,0.0005283594,0.0001210059,0.005310292],"genre_scores_gemma":[0.9927611,0.0007878098,0.004215396,0.00003323129,0.000005220027,0.00002520847,0.0002942312,0.0000252578,0.001852554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00104598,"threshold_uncertainty_score":0.00349915,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02456671398656571,"score_gpt":0.271541793059811,"score_spread":0.2469750790732453,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}