{"id":"W4251455858","doi":"10.1016/s0022-2860(03)00741-5","title":"A comment on the use of redundant vibrational coordinates","year":2004,"lang":"en","type":"article","venue":"Journal of Molecular Structure","topic":"Mechanical and Optical Resonators","field":"Physics and Astronomy","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Eigenvalues and eigenvectors; Cartesian coordinate system; Matrix (chemical analysis); Constant (computer programming); Generalized coordinates; Inverse; Constraint (computer-aided design); Action-angle coordinates; Zero (linguistics); Bipolar coordinates; Chemistry; Mathematical analysis; Classical mechanics; Physics; Geometry; Quantum mechanics; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.01173403,0.001534238,0.002363787,0.001497191,0.005280588,0.003377349,0.00811983,0.02051553,0.01212807],"category_scores_gemma":[0.04971095,0.001697451,0.002338719,0.0017944,0.01272766,0.008530644,0.003894266,0.03656691,0.01150467],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002284111,"about_ca_system_score_gemma":0.002503236,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006630389,"about_ca_topic_score_gemma":0.006027014,"domain_scores_codex":[0.9852374,0.002934769,0.001869403,0.002486401,0.006136467,0.001335439],"domain_scores_gemma":[0.9709047,0.01614791,0.002249233,0.003816521,0.006160954,0.0007206337],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0002539525,0.00004512171,0.0004710398,0.0005078333,0.0001175193,0.0009148063,0.001555441,0.000505105,0.002206125,0.4198703,0.5610906,0.0124622],"study_design_scores_gemma":[0.0002335894,0.0001117603,0.001429385,0.0006571161,0.00009838348,0.001457389,0.0005065592,0.001329586,0.003838329,0.2008461,0.7892742,0.0002175671],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"commentary","genre_gemma":"commentary","genre_scores_codex":[0.00349932,0.007159219,0.02653362,0.799894,0.1083713,0.00006438616,0.0009055816,0.000979508,0.0525931],"genre_scores_gemma":[0.06568327,0.004670219,0.0272269,0.7884905,0.07862464,0.0003727235,0.0003143008,0.001025891,0.03359167],"genre_candidate":"commentary","genre_consensus":"commentary","teacher_disagreement_score":0.02051553,"threshold_uncertainty_score":0.06205618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01460713710087577,"score_gpt":0.2306906221075948,"score_spread":0.216083485006719,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}