{"id":"W4252201143","doi":"10.1002/chin.200523040","title":"Evaluation of Ethyl 2-Carbomethoxyethenesulfinates as 2-Hydroxymethyl Enethiol Equivalents in the Diels—Alder Reaction.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Organic and Inorganic Chemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Hydroxymethyl; Diels–Alder reaction; Equivalent; Organic chemistry; Medicinal chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001784015,0.0002109512,0.0002391843,0.00007289836,0.0000659057,0.00002193106,0.0004441816,0.0002930902,0.002822842],"category_scores_gemma":[0.001880238,0.0001633256,0.0001279987,0.0003797308,0.0001026463,0.0002719916,0.00008165494,0.0005001251,0.0001145739],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004066294,"about_ca_system_score_gemma":0.0002195427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009453564,"about_ca_topic_score_gemma":0.00001719875,"domain_scores_codex":[0.9977755,0.000006095143,0.000558371,0.0002593513,0.001086,0.0003146723],"domain_scores_gemma":[0.9983655,0.0004861478,0.0002386502,0.0005772033,0.000260289,0.00007217633],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001629601,0.0001752753,0.00006767885,0.00004843175,0.00004690635,4.691286e-7,0.001969017,0.0000035543,0.7383674,0.0002238294,0.0009673567,0.2581138],"study_design_scores_gemma":[0.0008511683,0.00001280068,0.0003534082,0.00005539223,0.000138317,0.00001760722,0.001565001,0.0002496445,0.9746126,0.001562443,0.02039646,0.0001851839],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5014594,0.0004231976,9.993038e-7,0.0005326326,0.00005498076,0.0001069852,0.000006518913,0.00003603927,0.4973792],"genre_scores_gemma":[0.9962537,0.0002079802,0.000057972,0.0001943676,0.0002461024,0.00006084043,0.00003772129,0.000023681,0.002917588],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4947943,"threshold_uncertainty_score":0.9980887,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03661401432384085,"score_gpt":0.3126026335325852,"score_spread":0.2759886192087443,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}