{"id":"W4252594302","doi":"10.1002/ange.201808490","title":"The Diverse Reactivity of Disilenes Toward Isocyanides","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Deutscher Akademischer Austauschdienst; Alexander von Humboldt-Stiftung","keywords":"Isocyanide; Steric effects; Chemistry; Reactivity (psychology); Enamine; Ugi reaction; Bicyclic molecule; Medicinal chemistry; Stereochemistry; Photochemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003105311,0.0004679876,0.0001720456,0.0003027993,0.0001595832,0.0003081276,0.0003251753,0.0003102222,0.00136489],"category_scores_gemma":[0.0002807557,0.0001877724,0.0001722822,0.0001408917,0.0002290787,0.0002576166,0.0002251382,0.0003612614,0.0004254987],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002319331,"about_ca_system_score_gemma":0.0001644835,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004516031,"about_ca_topic_score_gemma":0.001072708,"domain_scores_codex":[0.9998229,0.00003669887,0.00001557192,0.00004144274,0.00004222596,0.000041116],"domain_scores_gemma":[0.9998287,0.00004582615,0.00003332757,0.00002328308,0.00003647132,0.00003231146],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008492886,0.000009247536,0.0001051444,0.0000316398,0.000006251386,0.00006946568,0.00003242931,0.00009704954,0.9980971,0.0001410712,0.00002176457,0.001303802],"study_design_scores_gemma":[0.000004716672,0.000134001,0.0005096672,0.000002769319,0.000006012332,0.00006510196,0.00001247935,0.000182964,0.9983593,0.00001682931,0.0007021209,0.000003873969],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907598,0.0009236309,0.001680958,0.00005074489,0.00001645219,0.00003481972,0.0001416234,0.00005235106,0.006339501],"genre_scores_gemma":[0.9954745,0.0007142748,0.00168339,0.00002539536,0.000005816901,0.00002179985,0.0002232649,0.00001801721,0.001833506],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00136489,"threshold_uncertainty_score":0.004566014,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02967477482728942,"score_gpt":0.2496022450527106,"score_spread":0.2199274702254211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}