{"id":"W4252975762","doi":"10.1139/cjc-78-1-128","title":"Mn(OAc)&lt;sub&gt;3&lt;/sub&gt;-promoted hydroxylation of α-carbomethoxy-&lt;FONT FACE=\"SYMBOL\"&gt;g&lt;/FONT&gt;-lactones by molecular oxygen","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Chemistry; Font; Hydroxylation; Symbol (formal); Oxygen; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001523816,0.001191977,0.001768985,0.0002335901,0.0002715049,0.0002012229,0.002042127,0.001272513,0.01062652],"category_scores_gemma":[0.001514729,0.001351645,0.000922158,0.000852527,0.0005962789,0.0003470405,0.00009427327,0.001454492,0.00004963494],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001378398,"about_ca_system_score_gemma":0.002523544,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001709089,"about_ca_topic_score_gemma":0.0001231699,"domain_scores_codex":[0.9929471,0.0002215972,0.002586863,0.001116628,0.001496122,0.001631711],"domain_scores_gemma":[0.992814,0.0003673535,0.001745617,0.001832676,0.0006526278,0.002587721],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001159903,0.0001687596,0.00009235106,0.0004788461,0.0005040428,0.0005095428,0.0006773355,0.0001466802,0.9767474,0.000006740258,0.00465912,0.01589319],"study_design_scores_gemma":[0.002046534,0.00006343425,0.0001407848,0.0006128986,0.0003882715,0.001426877,0.0002973036,0.0003264513,0.9644827,0.0005563657,0.02845057,0.001207866],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9611833,0.005980861,0.0002818465,0.00134033,0.0002490741,0.0002086626,0.0006169142,0.0000941164,0.03004491],"genre_scores_gemma":[0.9930654,0.0003196092,0.001883879,0.0001362459,0.0006875204,0.00001483212,0.0002585931,0.0002604559,0.003373485],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03188209,"threshold_uncertainty_score":0.9988933,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008738520850039283,"score_gpt":0.225291264691194,"score_spread":0.2165527438411547,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}