{"id":"W4253102655","doi":"10.1002/ange.202101054","title":"Reactions of B<sub>2</sub>(<i>o</i>‐tolyl)<sub>4</sub> with Boranes: Assembly of the Pentaborane(9), HB[B(<i>o</i>‐tolyl)(μ‐H)]<sub>4</sub>","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Deutsche Forschungsgemeinschaft; John Simon Guggenheim Memorial Foundation","keywords":"Diborane; Boranes; Borane; Chemistry; Hydride; Medicinal chemistry; Stereochemistry; Boron; Catalysis; Hydrogen; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007665793,0.0002574481,0.0001796975,0.00009801459,0.0001869613,0.0002247961,0.0002210224,0.0001638587,0.001752911],"category_scores_gemma":[0.0001163028,0.0002145246,0.0001260475,0.00009416402,0.0001753927,0.0001885843,0.0002663245,0.0002803676,0.0006650923],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001871594,"about_ca_system_score_gemma":0.000171026,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006279746,"about_ca_topic_score_gemma":0.001345659,"domain_scores_codex":[0.9999176,0.00001410156,0.00000376412,0.00001144241,0.00001293849,0.00004000511],"domain_scores_gemma":[0.9999504,0.000008041323,0.00001516915,0.000004871777,0.000005677256,0.00001580756],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001393151,0.00001644889,0.0001257414,0.00005242825,0.000007598725,0.00005126276,0.00004858147,0.0002989086,0.9976671,0.0002044916,0.00008100986,0.001307247],"study_design_scores_gemma":[0.00001173561,0.000145842,0.0003395448,0.000003190773,0.000007372685,0.00005878059,0.00002638548,0.0004634249,0.9970988,0.00006110589,0.001777852,0.000005928165],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917795,0.0004557436,0.002891117,0.00003619116,0.00004197016,0.00002781046,0.0001037789,0.00009259461,0.004571318],"genre_scores_gemma":[0.9928334,0.0002965947,0.002961059,0.00003407398,0.000004333044,0.00002578067,0.0001531384,0.00004693391,0.003644705],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001752911,"threshold_uncertainty_score":0.005864084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009432104660650708,"score_gpt":0.2131672266829528,"score_spread":0.2037351220223021,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}