{"id":"W4253177173","doi":"10.1002/ange.201410033","title":"The Phosphinoboration Reaction","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Mount Allison University; Newcastle University; University of New Brunswick","keywords":"Regioselectivity; Aldimine; Chemistry; Reactivity (psychology); Catalysis; Single bond; Transition metal; Double bond; Stereochemistry; Medicinal chemistry; Organic chemistry; Group (periodic table)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001665144,0.0006311138,0.0002018939,0.0003080472,0.0004569636,0.000308473,0.0003579055,0.000301746,0.008865483],"category_scores_gemma":[0.0001638572,0.0002437238,0.0001656145,0.0001592629,0.0002581472,0.0005075608,0.0006420449,0.0008490708,0.003480526],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003241146,"about_ca_system_score_gemma":0.0004791862,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005831562,"about_ca_topic_score_gemma":0.0009265667,"domain_scores_codex":[0.9998193,0.00001822446,0.00001251639,0.00005964997,0.00003234461,0.00005802878],"domain_scores_gemma":[0.9999568,0.000005282955,0.000006822895,0.000008196145,0.00001014146,0.00001280318],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002815963,0.00007368162,0.000355662,0.0006911277,0.00004421979,0.0007018266,0.0002467015,0.0005765882,0.9408894,0.01169089,0.003159658,0.04128865],"study_design_scores_gemma":[0.000040493,0.0002792408,0.0003552185,0.00002496515,0.00002684968,0.0008266687,0.00003397556,0.0003971082,0.939211,0.001111847,0.05767291,0.00001975392],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6542956,0.01449868,0.1562984,0.002805741,0.002108541,0.0008831957,0.002750921,0.002869103,0.1634899],"genre_scores_gemma":[0.9537281,0.002868799,0.0136508,0.0003515446,0.00004071774,0.0001116327,0.0007745479,0.0001173839,0.02835641],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008865483,"threshold_uncertainty_score":0.02965796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00881209157478944,"score_gpt":0.2085002960985095,"score_spread":0.19968820452372,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}