{"id":"W4253177173","doi":"10.1002/ange.201410033","title":"The Phosphinoboration Reaction","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Mount Allison University; Newcastle University; University of New Brunswick","keywords":"Regioselectivity; Aldimine; Chemistry; Reactivity (psychology); Catalysis; Single bond; Transition metal; Double bond; Stereochemistry; Medicinal chemistry; Organic chemistry; Group (periodic table)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000199258,0.0001289486,0.0001035608,0.00001075176,0.0003011085,0.00008674365,0.0002170301,0.00009531147,0.0002320692],"category_scores_gemma":[0.000235309,0.00009709126,0.00006025305,0.00009787109,0.00006149996,0.0001048395,0.00003958999,0.0001388257,0.0001894826],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009174661,"about_ca_system_score_gemma":0.00002116005,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004147822,"about_ca_topic_score_gemma":0.00002163847,"domain_scores_codex":[0.9991954,0.000008941693,0.0001659116,0.0002085397,0.0002008395,0.0002203495],"domain_scores_gemma":[0.99906,0.000248171,0.00009530574,0.0004822274,0.00005669001,0.00005754875],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001817597,0.00001714857,0.0003797365,0.00001176158,0.00001605255,5.407948e-7,0.00005654536,3.771192e-7,0.9854974,0.0004398918,0.005417074,0.00814527],"study_design_scores_gemma":[0.0001117659,0.000004198193,0.0001400296,0.000009124148,0.00001322578,0.000003319759,0.00005006772,0.00001937672,0.7314971,0.0007361748,0.2673207,0.00009495057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7261894,0.000590548,0.00007118134,0.002043741,0.0003333164,0.00005541122,0.000005260934,0.000335984,0.2703752],"genre_scores_gemma":[0.9942989,0.0001369239,0.000112157,0.00009703836,0.0004015533,0.00002147306,0.0000182019,0.00002818094,0.004885557],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2681095,"threshold_uncertainty_score":0.3959267,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00881209157478944,"score_gpt":0.2085002960985095,"score_spread":0.19968820452372,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}