{"id":"W4253490194","doi":"10.26434/chemrxiv.12724724","title":"Dynamic Ion Speciation During Hydrolysis of Aryltrifluoroborates","year":2020,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; British Columbia Knowledge Development Fund; University of Victoria","keywords":"Hydrolysis; Transmetalation; Chemistry; Electrospray ionization; Ion; Mass spectrometry; Electrospray; Boron; Inorganic chemistry; Chromatography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00008145125,0.0003317851,0.0005360394,0.0001101533,0.00007836198,0.00007579596,0.0003915445,0.0004476718,0.0006032341],"category_scores_gemma":[0.0002477555,0.0003967033,0.0003466497,0.0002411673,0.00009331447,0.00006832512,0.0004454968,0.0007708547,0.00008661725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004039013,"about_ca_system_score_gemma":0.0001426691,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000747482,"about_ca_topic_score_gemma":0.00001212091,"domain_scores_codex":[0.9981998,7.850612e-7,0.0005803172,0.0006686203,0.0003152752,0.000235196],"domain_scores_gemma":[0.9981748,0.00007877528,0.0006173878,0.0008824316,0.0001436148,0.0001029186],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003063739,0.00008140036,0.001465027,0.001241128,0.0001769646,0.000009278723,0.0002187803,0.002215148,0.9943267,0.00001031197,0.00006663218,0.0001580405],"study_design_scores_gemma":[0.0003117836,0.00000294715,0.002975638,0.0002695447,0.0002019127,0.000006181141,0.00007279139,0.01031515,0.9847602,0.0006812947,0.0000746722,0.0003278884],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973078,0.0003068912,0.00005193882,0.0002998004,0.0002631278,0.0001010644,0.0000507487,0.0002432428,0.001375406],"genre_scores_gemma":[0.9976344,0.0001576061,0.0001120113,0.000005170664,0.0003423797,0.00003644785,0.0008693665,0.00006975654,0.0007728549],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009566458,"threshold_uncertainty_score":0.9998485,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01363890275672218,"score_gpt":0.2563628782888457,"score_spread":0.2427239755321235,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}