{"id":"W4254293471","doi":"10.1002/ange.201709059","title":"Intramolecular Thioether Migration in the Rhodium‐Catalyzed Ene‐Cycloisomerization of Alkenylidenecyclopropanes by a Metal‐Mediated β‐Sulfide Elimination","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Canada Research Chairs; Engineering and Physical Sciences Research Council; China Scholarship Council; AstraZeneca","keywords":"Cycloisomerization; Allylic rearrangement; Sulfide; Thioether; Intramolecular force; Chemistry; Rhodium; Ene reaction; Catalysis; Selenide; Medicinal chemistry; Sulfur; Stereochemistry; Combinatorial chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001639164,0.0004019492,0.0001001288,0.0001274799,0.0001543944,0.0001618654,0.0002051839,0.0001879956,0.00190632],"category_scores_gemma":[0.000102041,0.0001076076,0.0001670899,0.0000836146,0.0002085688,0.0002197178,0.0002254929,0.0004097826,0.0005898258],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000135595,"about_ca_system_score_gemma":0.0002952584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003981077,"about_ca_topic_score_gemma":0.001008486,"domain_scores_codex":[0.9999157,0.00001156373,0.000004922968,0.00001666545,0.00001689431,0.00003423496],"domain_scores_gemma":[0.9999611,0.000007079889,0.000009835435,0.000007050592,0.000006951054,0.000007926786],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001205826,0.00008418166,0.0003242341,0.0001236071,0.00002363058,0.0005024511,0.0001352701,0.000329643,0.9859985,0.002352982,0.0004115534,0.009593323],"study_design_scores_gemma":[0.00001469934,0.0002825806,0.0006690882,0.000005744192,0.0000138591,0.0002891136,0.00002644151,0.0008175721,0.9937544,0.00008831455,0.004030899,0.000007281601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9723317,0.000842941,0.006469368,0.0001853508,0.00006953056,0.00004725669,0.00008133235,0.0001070867,0.01986543],"genre_scores_gemma":[0.995734,0.0003582716,0.001121262,0.00001931714,0.000007024806,0.000008557896,0.00004807039,0.00001058953,0.002693013],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00190632,"threshold_uncertainty_score":0.00637722,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.014375113273835,"score_gpt":0.2559996861047675,"score_spread":0.2416245728309325,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}