{"id":"W4254314623","doi":"10.1002/ange.201805569","title":"Reaction of CO<sub>2</sub> with a Vanadium(II) Aryl Oxide: Synergistic Activation of CO<sub>2</sub>/Oxo Groups towards H‐Atom Radical Abstraction","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Formate; Deoxygenation; Aryl; Medicinal chemistry; Vanadium; Hydrogen atom abstraction; Atom (system on chip); Stereochemistry; Radical; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005534761,0.0002850675,0.0001364311,0.00007326755,0.00008142462,0.000194575,0.0001535116,0.0001727822,0.0008943574],"category_scores_gemma":[0.00008327721,0.00009381324,0.00008698155,0.00006641063,0.0001294674,0.0001121314,0.0001407712,0.0001475225,0.000179504],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001421427,"about_ca_system_score_gemma":0.000109384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006631425,"about_ca_topic_score_gemma":0.001916586,"domain_scores_codex":[0.9999446,0.000005109084,0.000002694291,0.00001159415,0.00001033296,0.00002559658],"domain_scores_gemma":[0.999972,0.000005342725,0.000006655644,0.000002896924,0.000004741873,0.000008375711],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009404538,0.00001108385,0.00008841726,0.00003465734,0.000004333677,0.00004194482,0.00001089408,0.00006094536,0.9986537,0.00005448065,0.00004077911,0.0009047328],"study_design_scores_gemma":[0.000004817916,0.00006879462,0.0003822233,0.000001415406,0.000005012952,0.00003105172,0.000008559436,0.0003273989,0.9985495,0.00001190477,0.0006075373,0.000001794972],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962961,0.0003506176,0.001301867,0.00004180519,0.00003715338,0.00001412735,0.00005705826,0.00003584391,0.001865321],"genre_scores_gemma":[0.9984848,0.0001341315,0.0004278527,0.00001179571,0.00000314915,0.000004387483,0.00003719348,0.000005290735,0.0008915192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008943574,"threshold_uncertainty_score":0.002991974,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01351362381981125,"score_gpt":0.2386288121369569,"score_spread":0.2251151883171457,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}