{"id":"W4254448745","doi":"10.1002/chin.200451257","title":"Nanosecond Laser Flash Photolysis: A Tool for Physical Organic Chemistry","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Flash photolysis; Flash (photography); Nanosecond; Photodissociation; Laser; Photochemistry; Optics; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003005943,0.0002854026,0.0002248361,0.0005954329,0.0003755159,0.0005463627,0.0003858156,0.0004133914,0.005885235],"category_scores_gemma":[0.0004226773,0.0002702938,0.0002452439,0.0004733557,0.0004519866,0.0008643672,0.0004228034,0.001116485,0.001957577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006626216,"about_ca_system_score_gemma":0.0004167459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004222772,"about_ca_topic_score_gemma":0.0008283104,"domain_scores_codex":[0.9997469,0.00003167466,0.00000932579,0.00004517536,0.0001482697,0.00001869889],"domain_scores_gemma":[0.9997968,0.00009543484,0.00001847116,0.00003997183,0.00003600418,0.00001335364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001437419,0.00004800982,0.0003356819,0.0002492999,0.0000241922,0.00007775408,0.00006908537,0.000579875,0.8865276,0.01188385,0.005922791,0.09413815],"study_design_scores_gemma":[0.00001582536,0.00006437982,0.0005646007,0.00001551264,0.00001522314,0.0002175498,0.00002111449,0.00239076,0.9514378,0.002394134,0.04284777,0.0000153881],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.1975848,0.03373469,0.6728436,0.003547965,0.001661822,0.0002405699,0.002371835,0.007996717,0.08001801],"genre_scores_gemma":[0.6917136,0.02033945,0.2133621,0.0008443213,0.0003338217,0.0004600273,0.001616859,0.0007857641,0.07054407],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.005885235,"threshold_uncertainty_score":0.01968813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005748873795406663,"score_gpt":0.2146643061134686,"score_spread":0.2089154323180619,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}