{"id":"W4254645333","doi":"10.1002/chin.200622255","title":"Carbocations","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbocation; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00002014503,0.00008062367,0.00006818415,0.00001495562,0.00003654052,0.00001804507,0.0001088873,0.00008251466,0.003028922],"category_scores_gemma":[0.00003884117,0.00008145697,0.00005090573,0.00007405324,0.0000230061,0.0000681185,0.00002632428,0.00009672491,0.0002457742],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001001739,"about_ca_system_score_gemma":0.0000250153,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005596631,"about_ca_topic_score_gemma":0.00000457819,"domain_scores_codex":[0.9994649,1.918553e-8,0.0001465957,0.0001043961,0.0001296568,0.0001544176],"domain_scores_gemma":[0.9996164,0.00003010026,0.00004471592,0.0002228357,0.00003527214,0.00005063658],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000002777625,0.00003420897,0.00004137449,0.00002902016,0.000004794003,0.000001246641,0.00002259118,4.558575e-7,0.9453807,0.006102379,0.02016334,0.02821708],"study_design_scores_gemma":[0.0001170907,7.567733e-7,0.00001777788,0.000005599385,0.000005134593,0.000006818992,0.00003501022,0.00001940631,0.8238671,0.001610836,0.1742312,0.00008329366],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.02970767,0.00002234783,0.000007909708,0.00007284534,0.00003753168,0.00001475426,0.000005616247,0.0001678371,0.9699635],"genre_scores_gemma":[0.899683,0.000002750221,0.0001548058,0.00005308882,0.0002562845,0.00002246952,0.0001086785,0.00001299122,0.09970596],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.8702576,"threshold_uncertainty_score":0.9978824,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008009609437267622,"score_gpt":0.2196421728828845,"score_spread":0.2116325634456169,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}