{"id":"W4255319645","doi":"10.1139/cjc-79-4-349","title":"2000 Alfred Bader Award Lecture&lt;BR&gt;In the footsteps of Pasteur: asymmetric induction in the photochemistry of crystalline ammonium carboxylate salts","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemistry and Chemical Engineering","field":"Environmental Science","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Chemistry; Carboxylate; Ammonium; Asymmetric induction; Photochemistry; Stereochemistry; Organic chemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002221563,0.0007839668,0.0005252791,0.0006701701,0.001291086,0.001455262,0.0009515424,0.002395646,0.02194768],"category_scores_gemma":[0.001147283,0.0003320264,0.0004354859,0.0004142809,0.00109357,0.001436567,0.0009177515,0.005096814,0.01025396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002820639,"about_ca_system_score_gemma":0.00165969,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003742477,"about_ca_topic_score_gemma":0.006268937,"domain_scores_codex":[0.999387,0.00006059478,0.00002195303,0.0001372113,0.0002375315,0.0001556335],"domain_scores_gemma":[0.9990085,0.0001388071,0.00003497571,0.00003092647,0.0003734818,0.0004132994],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001144896,0.0002460488,0.0003385756,0.0001897512,0.00003356492,0.0001813781,0.0001710816,0.0003773357,0.02671367,0.02037467,0.7739575,0.1762716],"study_design_scores_gemma":[0.0001181023,0.0005271831,0.0009241849,0.00005619754,0.0000318213,0.0001750315,0.0001099799,0.0006988286,0.0412475,0.004524033,0.9515429,0.00004423523],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"commentary","genre_gemma":"empirical","genre_scores_codex":[0.03204572,0.1141484,0.0160203,0.4016302,0.202977,0.0002054461,0.0005577388,0.0006876516,0.2317275],"genre_scores_gemma":[0.09373516,0.03951316,0.004683735,0.01652572,0.03565831,0.00004655821,0.0003148096,0.0002718997,0.8092507],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.02194768,"threshold_uncertainty_score":0.07342231,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006150647779505725,"score_gpt":0.1808941714205259,"score_spread":0.1747435236410201,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}