{"id":"W4255534459","doi":"10.1002/chin.200603243","title":"Antiaromaticity Effects in Cyclopentadienyl Carbocations and Free Radicals","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Antiaromaticity; Carbocation; Cyclopentadienyl complex; Radical; Photochemistry; Organic chemistry; Aromaticity; Molecule; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003618646,0.0002635758,0.0002060746,0.0003027566,0.0002279829,0.0002420165,0.0002873093,0.0003085574,0.007348991],"category_scores_gemma":[0.0002921013,0.0001165396,0.0002377089,0.0001462389,0.0003363586,0.000303219,0.0001822717,0.0003553129,0.0004390723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001878334,"about_ca_system_score_gemma":0.0001554646,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005805671,"about_ca_topic_score_gemma":0.000457804,"domain_scores_codex":[0.9998776,0.00003163445,0.000006236136,0.00001738206,0.00001721849,0.00005003486],"domain_scores_gemma":[0.9997109,0.00009616709,0.00005837013,0.00003795379,0.00003793924,0.00005867688],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003657735,0.0002056189,0.0003588411,0.0002423911,0.00005752846,0.0003363136,0.0001208257,0.0006423345,0.985568,0.002275519,0.0005471092,0.005987728],"study_design_scores_gemma":[0.0003429871,0.005221751,0.001903055,0.00002564017,0.00008333061,0.0003831246,0.0001000086,0.0006269071,0.984872,0.0005926329,0.005823648,0.00002489467],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919297,0.003100958,0.0004767397,0.0001119706,0.00009483299,0.00002102318,0.0001040648,0.00004138989,0.00411934],"genre_scores_gemma":[0.9967319,0.0008167546,0.0001238934,0.00003662863,0.00002532842,0.000004875479,0.00007148922,0.00001017162,0.002179064],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007348991,"threshold_uncertainty_score":0.02458483,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008102945345548646,"score_gpt":0.2147078046552504,"score_spread":0.2066048593097018,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}