{"id":"W4255835109","doi":"10.32920/ryerson.14645448.v1","title":"Group 11 Pincer Oxazoline Complexes","year":2021,"lang":"en","type":"preprint","venue":"","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"","keywords":"Pincer movement; Nitroaldol reaction; Chemistry; Oxazoline; Reactivity (psychology); Catalysis; Ligand (biochemistry); Pincer ligand; Single crystal; Polymer chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Crystallography; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009067771,0.0003995376,0.0003032104,0.0002480654,0.0002228086,0.0007525269,0.0005044797,0.0002968549,0.003970795],"category_scores_gemma":[0.0002660582,0.0001309711,0.0001255502,0.0002311842,0.0002247959,0.0002965791,0.0005526493,0.0003887778,0.0008097347],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000603305,"about_ca_system_score_gemma":0.0001945776,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006132135,"about_ca_topic_score_gemma":0.0006991466,"domain_scores_codex":[0.9998272,0.00001606572,0.00001138067,0.00003351538,0.00005031706,0.00006165474],"domain_scores_gemma":[0.9999394,0.000005892503,0.00001758254,0.000006902911,0.00001396733,0.00001616095],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005779356,0.00007832735,0.0005355005,0.0006721501,0.00003352942,0.0009624309,0.0003361358,0.001036153,0.9628304,0.006543944,0.002072295,0.02432119],"study_design_scores_gemma":[0.00006657877,0.0006214589,0.0008757188,0.00002611368,0.00003291842,0.001151152,0.00007359828,0.0006889001,0.9497036,0.0003391697,0.04639298,0.00002783275],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9477266,0.006012875,0.007698678,0.0003239891,0.0001418108,0.0001202378,0.0005396345,0.0003741092,0.037062],"genre_scores_gemma":[0.9761938,0.001682438,0.00315046,0.0001025818,0.00001774992,0.00005236701,0.0005748792,0.00005244858,0.01817311],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003970795,"threshold_uncertainty_score":0.01328367,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02395548009101672,"score_gpt":0.2456606972838404,"score_spread":0.2217052171928237,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}