{"id":"W4256571784","doi":"10.26434/chemrxiv.14317649.v1","title":"Optical Spectroscopy of Crystal Nucleation One Nucleus at a Time","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Crystallization and Solubility Studies","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Université de Genève; Compute Canada","keywords":"Nucleation; Crystallization; Nucleus; Raman spectroscopy; Crystal (programming language); Spectroscopy; Chemical physics; Materials science; Crystallography; Chemistry; Physics; Computer science; Optics; Thermodynamics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002597783,0.0002121668,0.0005263222,0.00004724338,0.00009806041,0.0001019199,0.0002505048,0.0002146756,0.008384263],"category_scores_gemma":[0.0002508636,0.0002271635,0.0001628953,0.0001005666,0.0002514248,0.00006204541,0.001133879,0.0001646011,0.0001837782],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002116131,"about_ca_system_score_gemma":0.0001030986,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001795506,"about_ca_topic_score_gemma":0.00002072437,"domain_scores_codex":[0.9983401,0.00005132669,0.0004439732,0.0005485121,0.0003786171,0.0002374984],"domain_scores_gemma":[0.9988493,0.00006475078,0.0002121889,0.0005630648,0.0002273135,0.00008341343],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003828561,0.0001972561,0.0001505981,0.0002766678,0.00002961738,0.000003751645,0.0008737051,0.00008878091,0.9974908,0.0001989643,0.0006306367,0.00002094674],"study_design_scores_gemma":[0.0002967441,0.0000422286,0.002432243,0.0001820777,0.00007174964,0.000003129219,0.0001869685,0.0006846525,0.9945189,0.0003964303,0.0008856138,0.0002992699],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898502,0.0001680129,0.001113653,0.0003395779,0.0002923653,0.0002375802,0.00001902471,0.0001123301,0.007867235],"genre_scores_gemma":[0.9883982,0.00007489864,0.009729299,0.0000568476,0.0001316243,0.00001844327,0.0001129685,0.0000309585,0.001446787],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008615646,"threshold_uncertainty_score":0.9925222,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02412627785025725,"score_gpt":0.2630699226397726,"score_spread":0.2389436447895153,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}