{"id":"W4280567527","doi":"10.1016/j.chroma.2022.463153","title":"Analysis of the solvent strength parameter (linear solvent strength model) for isocratic separations in reversed-phase liquid chromatography","year":2022,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":false,"ca_institutions":"CanAm Bioresearch (Canada)","funders":"","keywords":"Chemistry; Solvent; Acetonitrile; Solvation; Tetrahydrofuran; Acetone; Solvent effects; Chromatography; Analytical Chemistry (journal); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002359076,0.0008214242,0.0006693527,0.001010757,0.0003753989,0.0008846443,0.0009998698,0.001138014,0.0007910192],"category_scores_gemma":[0.00647911,0.0004717094,0.0009243794,0.0007534128,0.0005334353,0.001335829,0.0005371484,0.001416082,0.0006448808],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007577578,"about_ca_system_score_gemma":0.001157476,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009402793,"about_ca_topic_score_gemma":0.0007973455,"domain_scores_codex":[0.99828,0.0006285846,0.0001001446,0.0001927465,0.0007344467,0.00006392117],"domain_scores_gemma":[0.9973043,0.001449352,0.0003223073,0.0002946284,0.0005634406,0.00006593249],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002061741,0.001014382,0.0103259,0.0008761771,0.0003798227,0.0003530561,0.0001021796,0.06604613,0.7619576,0.00608159,0.0018438,0.1489576],"study_design_scores_gemma":[0.000052345,0.0005645361,0.005507471,0.00002903574,0.0001627893,0.0003842203,0.00003696168,0.4265637,0.5618082,0.002448648,0.002364057,0.00007805959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.3164373,0.003718776,0.6742144,0.0003313885,0.0001153343,0.000228776,0.0004223267,0.001886815,0.002644829],"genre_scores_gemma":[0.89965,0.00129084,0.09596151,0.0001902544,0.00004454074,0.0002105301,0.0008606365,0.0003365225,0.001455077],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.002359076,"threshold_uncertainty_score":0.01247615,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01792164408514472,"score_gpt":0.2864603359438135,"score_spread":0.2685386918586688,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}