{"id":"W4280583290","doi":"10.1002/ange.202205194","title":"Controlling the Structure, Properties and Surface Reactivity of Clickable Azide‐Functionalized Au<sub>25</sub>(SR)<sub>18</sub> Nanocluster Platforms Through Regioisomeric Ligand Modifications","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Nanoclusters; Chemistry; Cycloaddition; Azide; Ligand (biochemistry); Alkyne; Moiety; Reactivity (psychology); Crystallography; Stereochemistry; Crystal structure; Click chemistry; Cluster (spacecraft); Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005542712,0.0002877676,0.0004553046,0.000048158,0.001129463,0.0001102194,0.0004111166,0.00009281949,0.0001042989],"category_scores_gemma":[0.00009061286,0.0002030077,0.000125972,0.0003922825,0.0003640085,0.0004513417,0.0002945917,0.0002328683,0.00001285378],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001467226,"about_ca_system_score_gemma":0.0001613165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001735219,"about_ca_topic_score_gemma":0.00006519095,"domain_scores_codex":[0.9979544,0.00007456177,0.0005154076,0.0005601652,0.0004819456,0.0004135634],"domain_scores_gemma":[0.9983138,0.0003124473,0.0004549031,0.0006944963,0.0001441777,0.00008019686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001387053,0.00009521405,0.0001414437,0.00005558505,0.00004056756,7.099698e-7,0.001030364,0.0005804089,0.9958641,0.0003242918,0.00144556,0.0002830316],"study_design_scores_gemma":[0.0007714071,0.00004525526,0.0002406138,0.00003033071,0.000092286,0.00002922974,0.000547494,0.0001382559,0.9911852,0.001641526,0.005014205,0.0002642292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952749,0.001363814,0.0006091475,0.0008629944,0.0002051746,0.0007573153,0.0002233851,0.00007216575,0.0006310837],"genre_scores_gemma":[0.9984952,0.0002953337,0.0002110607,0.0002606401,0.00011972,0.0002538374,0.00003685164,0.00003837456,0.0002890296],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004678951,"threshold_uncertainty_score":0.8687028,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04364416609016751,"score_gpt":0.2364387089017548,"score_spread":0.1927945428115873,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}