{"id":"W4280583305","doi":"10.1007/s43630-022-00237-9","title":"Photosensitized selective semi-oxidation of tetrahydroisoquinoline: a singlet oxygen path","year":2022,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University; University of Ottawa","funders":"Generalitat Valenciana; Dirección General de Universidades e Investigación; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Singlet oxygen; Photochemistry; Catalysis; Chemistry; Singlet state; Oxygen; Organic chemistry; Excited state","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000125627,0.0001588104,0.00011434,0.00008431287,0.0001243052,0.0001647373,0.0003727781,0.0002472661,0.001883962],"category_scores_gemma":[0.0000918659,0.0000811294,0.0001292688,0.00006290396,0.0001393687,0.0001800347,0.0001405144,0.0003129271,0.0002972993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002662633,"about_ca_system_score_gemma":0.0001621721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000928491,"about_ca_topic_score_gemma":0.001202712,"domain_scores_codex":[0.9999348,0.000008581764,0.000002404999,0.00001806121,0.00001422001,0.00002194797],"domain_scores_gemma":[0.9999468,0.00001259459,0.00000860895,0.000009774542,0.00001345522,0.000008789537],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008336056,0.0000140218,0.00005841697,0.00002669547,0.000002126014,0.00003642733,0.00001656166,0.00005389096,0.9979353,0.000404598,0.00009572551,0.001272808],"study_design_scores_gemma":[0.000009898468,0.0001677478,0.0004641304,0.000002061813,0.000004341701,0.0000825016,0.00001294616,0.0007647653,0.9967836,0.0001035259,0.001601263,0.00000312103],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851487,0.0008453123,0.009757729,0.0001376794,0.00005537772,0.00003204021,0.0001301009,0.000162563,0.003730394],"genre_scores_gemma":[0.9958432,0.0001772367,0.001503262,0.00003427787,0.000003812821,0.000007651915,0.0001074881,0.000009874654,0.002313279],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001883962,"threshold_uncertainty_score":0.006302476,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02075988191355513,"score_gpt":0.2581419882838029,"score_spread":0.2373821063702477,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}