{"id":"W4280618815","doi":"10.1016/j.ceja.2022.100322","title":"Role of redox reactions involving interfacial oxygen migration in ignition of nanolayered Al/a-Al2O /CuO energetic composite","year":2022,"lang":"en","type":"article","venue":"Chemical Engineering Journal Advances","topic":"Energetic Materials and Combustion","field":"Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Thermite; Exothermic reaction; Materials science; Redox; Metastability; Oxidizing agent; Chemical physics; Ignition system; Diffusion; Amorphous solid; Chemical engineering; Chemical kinetics; Kinetics; Chemical reaction; Activation energy; Thermodynamics; Physical chemistry; Aluminium; Composite material; Chemistry; Metallurgy; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009704949,0.000267776,0.0001682419,0.0002111253,0.0002556778,0.0003817693,0.0002739446,0.0002803833,0.0007069205],"category_scores_gemma":[0.0001732905,0.0001978955,0.0002336951,0.00009460324,0.0002163954,0.0003441162,0.0001713482,0.0002231635,0.00008076613],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005330889,"about_ca_system_score_gemma":0.0002957185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002409199,"about_ca_topic_score_gemma":0.002237249,"domain_scores_codex":[0.999969,0.000002815818,0.000001513974,0.000007117245,0.000009581137,0.00001003007],"domain_scores_gemma":[0.9999518,0.00001556846,0.00001297249,0.000002875438,0.000006580493,0.00001012432],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006897935,0.0002746837,0.007866465,0.0002959858,0.00007903616,0.0004766823,0.0002234446,0.1667985,0.8124248,0.003601326,0.0001744597,0.007094865],"study_design_scores_gemma":[0.00006697744,0.0002741805,0.006787714,0.00001405437,0.00004112461,0.00007278351,0.0001411776,0.7093618,0.2815744,0.0008451039,0.0007896234,0.00003113451],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998,0.0001156014,0.001023527,0.00002518636,0.00000808896,0.000004795092,0.00003538356,0.00003765394,0.0007497726],"genre_scores_gemma":[0.9992535,0.00006000287,0.0004678315,0.000004041114,8.489072e-7,0.000004376588,0.00002608274,0.000006189561,0.0001773019],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002409199,"threshold_uncertainty_score":0.004790366,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003663206421859893,"score_gpt":0.1832261820726072,"score_spread":0.1795629756507473,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}