{"id":"W4281614296","doi":"10.1007/s12274-022-4421-4","title":"Size matters: Steric hindrance of precursor molecules controlling the evolution of CdSe magic-size clusters and quantum dots","year":2022,"lang":"en","type":"article","venue":"Nano Research","topic":"Quantum Dots Synthesis And Properties","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Steric effects; Chemistry; Quantum dot; Cadmium selenide; Selenide; Molecule; Carboxylic acid; Nanotechnology; Stereochemistry; Selenium; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003688066,0.0001108471,0.0002769335,0.00009187158,0.0003652775,0.0000712171,0.0005420456,0.00003679437,0.000655504],"category_scores_gemma":[0.0006283923,0.00007390566,0.00005713424,0.0003091429,0.0005677399,0.0001400154,0.0003960541,0.0002061886,0.00001872641],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001086648,"about_ca_system_score_gemma":0.0001336078,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009937565,"about_ca_topic_score_gemma":0.00001948664,"domain_scores_codex":[0.9967007,0.001267337,0.0003655424,0.0002940011,0.0009840011,0.0003884194],"domain_scores_gemma":[0.9976173,0.0016013,0.0001603915,0.0003775371,0.0001954502,0.00004801053],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007267014,0.00007035356,0.0003041395,0.0001669605,0.00001159126,0.00000263838,0.001498419,0.0001807338,0.9947894,0.0009201869,0.0006302179,0.0006986418],"study_design_scores_gemma":[0.002948422,0.001996273,0.0112299,0.0004210444,0.00006194146,0.00005227269,0.01725299,0.02001194,0.9325829,0.006761632,0.006126319,0.0005543194],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923465,0.004266234,0.00008214533,0.00225647,0.0001656086,0.0004765661,0.00006363043,0.00001391245,0.0003289124],"genre_scores_gemma":[0.9989755,0.000103833,0.0002001843,0.0000776772,0.00002818091,0.00007870497,4.771718e-7,0.00001662642,0.0005188199],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06220647,"threshold_uncertainty_score":0.7177309,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0384192145311108,"score_gpt":0.2987811868381922,"score_spread":0.2603619723070814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}