{"id":"W4281620403","doi":"10.1002/cbic.202200202","title":"Histidine Ligated Iron‐Sulfur Peptides","year":2022,"lang":"en","type":"article","venue":"ChemBioChem","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Simons Foundation","keywords":"Histidine; Cysteine; Chemistry; Sulfur; Cofactor; Iron–sulfur cluster; Peptide; Biochemistry; Metalloprotein; Redox; Extant taxon; Combinatorial chemistry; Amino acid; Organic chemistry; Biology; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002507088,0.0002493335,0.0002851946,0.00007611047,0.0003305861,0.00003482652,0.0004584258,0.00007008555,0.008271553],"category_scores_gemma":[0.00007685965,0.0002575122,0.0001681084,0.00034676,0.00006677349,0.00007091105,0.0004172181,0.000320114,0.000370007],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001917493,"about_ca_system_score_gemma":0.00005839087,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00032057,"about_ca_topic_score_gemma":0.00001807761,"domain_scores_codex":[0.9983162,0.00005975028,0.0003264672,0.0004680817,0.0003810665,0.0004484733],"domain_scores_gemma":[0.9990434,0.00003003272,0.0001258654,0.000597333,0.0000448089,0.0001585547],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006755472,0.0002649075,0.00009145855,0.00006122832,0.00005906576,0.00004985748,0.000357181,0.0004389873,0.9283233,0.02335403,0.04209925,0.004833179],"study_design_scores_gemma":[0.0004455117,0.00008330361,0.0001029174,0.000005176295,0.00001819599,0.00002172773,0.0001801152,0.0001466882,0.6545318,0.0005190028,0.343699,0.0002465299],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8989425,0.001308334,0.00002146786,0.0008324419,0.0003585088,0.0001903967,0.00002246832,0.0002759879,0.0980479],"genre_scores_gemma":[0.9519722,0.0000225873,0.0004623702,0.0005461109,0.0002648547,0.0001586217,0.0001756044,0.00006384643,0.04633383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3015997,"threshold_uncertainty_score":0.9999877,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01410743928871948,"score_gpt":0.2122912421953396,"score_spread":0.1981838029066201,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}