{"id":"W4281631285","doi":"10.1002/celc.202200577","title":"Single Entity Electrochemical Detection of As‐prepared Metallic and Dielectric Nanoparticle Stochastic Impacts in a Phosphonium Ionic Liquid","year":2022,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Ionic liquid; Phosphonium; Front cover; Ultramicroelectrode; Dielectric; Nanoparticle; Electrochemistry; Materials science; Ionic bonding; Metal; Nanotechnology; Chemical engineering; Cover (algebra); Chemistry; Electrode; Polymer chemistry; Ion; Optoelectronics; Engineering; Physical chemistry; Organic chemistry; Metallurgy; Cyclic voltammetry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002155196,0.00029655,0.0004884421,0.0001587547,0.0002151922,0.00003244169,0.0003623838,0.0001203388,0.0003806138],"category_scores_gemma":[0.0001811714,0.0003311463,0.0001867099,0.001466406,0.00008986732,0.00009991848,0.0002125711,0.0006733957,0.000007024857],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000568444,"about_ca_system_score_gemma":0.0001485532,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009706836,"about_ca_topic_score_gemma":0.0000661142,"domain_scores_codex":[0.9975281,0.00003303023,0.0005791448,0.0006552599,0.0004578279,0.000746583],"domain_scores_gemma":[0.9989381,0.0001331796,0.0002664283,0.0004098151,0.00007333556,0.0001791594],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004219354,0.0006552801,0.00003136146,0.00005635989,0.00008860309,0.000001733579,0.0001899295,0.000009973687,0.9979547,0.0001936823,0.00001064122,0.0003857837],"study_design_scores_gemma":[0.0007425544,0.0004233634,0.00001612714,0.00001239639,0.000118021,0.00005564178,0.0001057297,0.001687424,0.9951213,0.001200395,0.000200774,0.0003162433],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962578,0.002594096,0.0002139665,0.0001232225,0.000009555149,0.0001529475,0.000004526562,0.00009461741,0.0005492747],"genre_scores_gemma":[0.9991446,0.00007530817,0.00005119183,0.00006719474,0.00004476365,0.0003649659,0.00005835881,0.00003990739,0.0001537458],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00288677,"threshold_uncertainty_score":0.9999141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005829067773069571,"score_gpt":0.2151889150339018,"score_spread":0.2093598472608322,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}