{"id":"W4281697463","doi":"10.3390/polym14112217","title":"Meso- and Rac-[bis(3-phenyl-6-tert-butylinden-1-yl)dimethylsilyl]zirconium Dichloride: Precatalysts for the Production of Differentiated Polyethylene Products with Enhanced Properties","year":2022,"lang":"en","type":"article","venue":"Polymers","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Agence Nationale de la Recherche","keywords":"Methylaluminoxane; Zirconium; Metallocene; Toluene; Polymer chemistry; Polymerization; Polyethylene; Linear low-density polyethylene; Materials science; Ethylene; Polymer; Copolymer; Olefin fiber; Catalysis; Chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003344762,0.0003435917,0.0004995976,0.0001217848,0.0005599647,0.00005253865,0.0004348049,0.00005650422,0.002011337],"category_scores_gemma":[0.000218528,0.0002313523,0.0001382555,0.0004808831,0.000303876,0.0001567767,0.0002573936,0.0002180616,0.00000159542],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007558791,"about_ca_system_score_gemma":0.0001526625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000241202,"about_ca_topic_score_gemma":0.00004183124,"domain_scores_codex":[0.9977823,0.00006528272,0.0004690811,0.0007432901,0.0005200367,0.0004199511],"domain_scores_gemma":[0.9983752,0.0001743556,0.0003969479,0.0008363039,0.0001342109,0.00008299213],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006417774,0.0002291173,0.0002030753,0.0003533983,0.000706898,6.126317e-7,0.001642208,0.00001802626,0.9710265,0.00002630913,0.00005249671,0.02509962],"study_design_scores_gemma":[0.0005743013,0.0001061786,0.0006956129,0.00004647037,0.0006080871,0.00001670513,0.002452624,0.00007449184,0.9928195,0.00001105541,0.002267412,0.0003275673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9882795,0.008634152,0.0001123405,0.001476117,0.0003017984,0.0005979695,0.00008729288,0.00009549098,0.0004153436],"genre_scores_gemma":[0.9834424,0.0001048622,0.0000743384,0.00002580879,0.0001955129,0.0007025936,0.000082029,0.00007109769,0.01530131],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02477205,"threshold_uncertainty_score":0.9989009,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01707992947382947,"score_gpt":0.2046909495070992,"score_spread":0.1876110200332698,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}