{"id":"W4281754950","doi":"10.26434/chemrxiv-2022-hmwkr-v2","title":"Photoinduced Oxygen Transfer using Nitroarenes for the Anaerobic Cleavage of Alkenes","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"York University; Princeton University; New York University","keywords":"Chemistry; Photochemistry; Cycloaddition; Cleavage (geology); Reagent; Regioselectivity; Alkene; Ozonolysis; Aryl; Photoexcitation; Combinatorial chemistry; Oxygen; Organic chemistry; Catalysis; Excited state","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002521622,0.0004315517,0.0001640198,0.000191745,0.0001660914,0.0002164039,0.0003068004,0.0003664245,0.001357866],"category_scores_gemma":[0.0001589433,0.0001597284,0.0002188407,0.0001250261,0.0002435812,0.0004033725,0.0004115732,0.0008350421,0.0004786904],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002248801,"about_ca_system_score_gemma":0.0002849295,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002578684,"about_ca_topic_score_gemma":0.000602378,"domain_scores_codex":[0.9998423,0.00001719024,0.000008648914,0.00004057217,0.00004687551,0.00004434048],"domain_scores_gemma":[0.9999235,0.0000161026,0.00002438858,0.00001359849,0.000009540337,0.00001280622],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003652571,0.00003123236,0.00007895847,0.00008805127,0.000006187307,0.0001192633,0.0000631549,0.0001553651,0.994081,0.0008696476,0.0000944637,0.004376215],"study_design_scores_gemma":[0.00001016662,0.0001427557,0.0002598571,0.000005501107,0.000006170562,0.0001657539,0.00001772086,0.000510584,0.9947689,0.0001265774,0.003978185,0.000007855107],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9136208,0.004643416,0.06807753,0.0003512116,0.000166395,0.0001597465,0.0002440726,0.0002662529,0.01247048],"genre_scores_gemma":[0.9825667,0.001504188,0.01282138,0.00006375062,0.00001748282,0.00003787845,0.000141859,0.00003589264,0.002810907],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001357866,"threshold_uncertainty_score":0.00454247,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05788477470166088,"score_gpt":0.2993934139087479,"score_spread":0.241508639207087,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}