{"id":"W4281769014","doi":"10.26434/chemrxiv-2022-15cwv-v2","title":"Mechanochemical synthesis of structurally well-defined graphitic phosphorus-linked carbon nitride (g-PCN) with water splitting activity","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Advanced Photocatalysis Techniques","field":"Energy","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; McGill University","funders":"Fonds de recherche du Québec – Nature et technologies; Centre in Green Chemistry and Catalysis; Compute Canada; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"X-ray photoelectron spectroscopy; Graphitic carbon nitride; Materials science; Water splitting; Powder diffraction; Magic angle spinning; Phosphide; Cyanuric chloride; Carbon nitride; Photocatalysis; Nitride; Chemical engineering; Catalysis; Heteroatom; Crystallography; Chemistry; Nanotechnology; Metal; Nuclear magnetic resonance spectroscopy; Organic chemistry; Polymer chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005087615,0.0001935764,0.00007667232,0.00009964305,0.00007265487,0.00009913646,0.0001834839,0.0001834085,0.0004397678],"category_scores_gemma":[0.00008393655,0.00008800786,0.00008835986,0.0001233334,0.0001287617,0.0001482435,0.0001325414,0.0002237769,0.0001223362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001976754,"about_ca_system_score_gemma":0.0001428171,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003627446,"about_ca_topic_score_gemma":0.001714298,"domain_scores_codex":[0.9999604,0.000003013022,0.000002094105,0.00001139533,0.00001623612,0.000006832217],"domain_scores_gemma":[0.9999762,0.000003927408,0.000008592446,0.000003364308,0.000003952467,0.000004070584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008435484,0.00001022571,0.00006263232,0.00005515055,0.00000211186,0.00003015026,0.000006742668,0.0003368095,0.9963865,0.0003176093,0.00004840307,0.002735171],"study_design_scores_gemma":[0.000002892997,0.00005402658,0.0007420842,0.000002286699,0.000002975699,0.0000567915,0.000005580926,0.001418987,0.9960741,0.00006081275,0.001576852,0.000002719635],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851167,0.0009106951,0.009188147,0.00007588687,0.00003362992,0.00006140456,0.0002881117,0.0001215846,0.004203969],"genre_scores_gemma":[0.9860481,0.0004977791,0.01153522,0.00002482476,0.000005640631,0.00003828813,0.0002472231,0.000025894,0.001576984],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004397678,"threshold_uncertainty_score":0.001471162,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01032354730474448,"score_gpt":0.2353333711542539,"score_spread":0.2250098238495095,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}