{"id":"W4281775668","doi":"10.1139/cjc-2022-0095","title":"Reaction of bis(dialkylphosphino)amines R<sub>2</sub>PNHPR<sub>2</sub> (R = <i>i</i>-Pr, <i>t</i>-Bu, Ph) with halogens X<sub>2</sub> (X = Cl, Br, I): different solvents – different stories","year":2022,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"","keywords":"Chemistry; Halogen; Dichloromethane; Methanol; Cationic polymerization; Medicinal chemistry; Nuclear magnetic resonance spectroscopy; Crystallography; X-ray crystallography; Stereochemistry; Solvent; Alkyl; Organic chemistry; Diffraction","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003867719,0.001076071,0.001399028,0.0002880004,0.0008228583,0.0001887084,0.001256508,0.0005096756,0.0005407563],"category_scores_gemma":[0.0003586119,0.001082926,0.000757244,0.0007473108,0.0005097379,0.0003983453,0.0002300404,0.001948846,0.000005144759],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001870366,"about_ca_system_score_gemma":0.001883209,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001674639,"about_ca_topic_score_gemma":0.001334702,"domain_scores_codex":[0.9944826,0.0000802291,0.001760823,0.0009077298,0.001519415,0.00124921],"domain_scores_gemma":[0.9940587,0.0002641308,0.002061421,0.001050315,0.0008343316,0.001731103],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003509588,0.0004498329,0.004706515,0.0008117549,0.0005984755,0.0003778683,0.0004873366,0.0001743443,0.9853421,0.000008651818,0.002947558,0.003744569],"study_design_scores_gemma":[0.002396615,0.0001592695,0.001436688,0.0003473919,0.000462222,0.0009753652,0.001294194,0.00002916201,0.9862396,0.0001210926,0.005469327,0.001069118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945481,0.001734232,0.00005939565,0.0005889542,0.0008146413,0.0001874686,0.0008787357,0.00007414833,0.001114356],"genre_scores_gemma":[0.9971707,0.0005571499,0.00001558551,0.0001570563,0.001072321,0.00006322893,0.0005099781,0.0001956649,0.0002582445],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003269827,"threshold_uncertainty_score":0.9991621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008992761151149985,"score_gpt":0.1910953025785457,"score_spread":0.1821025414273957,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}