{"id":"W4281790932","doi":"10.3762/bxiv.2022.45.v1","title":"Mechanochemical bottom-up synthesis of phosphorus-linked, heptazine-based carbon nitrides using sodium phosphide","year":2022,"lang":"en","type":"preprint","venue":"","topic":"MXene and MAX Phase Materials","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; NanoQuébec (Canada); McGill University; Centre in Green Chemistry and Catalysis","funders":"Centre in Green Chemistry and Catalysis; Compute Canada; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"X-ray photoelectron spectroscopy; Phosphide; Materials science; Photocatalysis; Photoluminescence; Photocurrent; Carbon nitride; Nitride; Spectroscopy; Annealing (glass); Analytical Chemistry (journal); Chemical engineering; Nanotechnology; Chemistry; Catalysis; Metallurgy; Optoelectronics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001648973,0.0007698669,0.001624489,0.0002984477,0.0001671541,0.0001783899,0.001300077,0.0005605918,0.01006664],"category_scores_gemma":[0.0005440982,0.000740061,0.0004768075,0.0002604371,0.0002190857,0.00008182531,0.002038533,0.0005430289,0.00003123768],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003418988,"about_ca_system_score_gemma":0.00101833,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.007547397,"about_ca_topic_score_gemma":0.00001893621,"domain_scores_codex":[0.9950412,0.0003494531,0.00144697,0.00132178,0.001054645,0.0007859421],"domain_scores_gemma":[0.9965599,0.0004294014,0.0009667909,0.001556758,0.0002555214,0.0002316174],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004387639,0.0002378685,0.00006234158,0.0005787728,0.00005813809,0.00002965662,0.00006496922,0.0005849567,0.996876,0.0003504632,0.0005512491,0.0001668429],"study_design_scores_gemma":[0.0006113218,0.00005314498,0.000006371309,0.0002669915,0.0003363505,0.00000673929,0.0001177747,0.002878958,0.9923543,0.001605385,0.0009821205,0.0007805683],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902818,0.0007349785,0.0006820536,0.0001763777,0.003995743,0.0008484815,0.0006268359,0.0003604856,0.002293221],"genre_scores_gemma":[0.9822349,0.0001406942,0.01604458,0.000253455,0.0003230399,0.0003548175,0.0001046334,0.0001358738,0.0004080099],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01536253,"threshold_uncertainty_score":0.999505,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03572361058090266,"score_gpt":0.2821177625991541,"score_spread":0.2463941520182514,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}