{"id":"W4282938263","doi":"10.1002/anie.202205963","title":"The Synthetic Potential of Thiophenium Ylide Cycloadducts**","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; University of Ottawa","keywords":"Cycloaddition; Ylide; Intramolecular force; Chemistry; Combinatorial chemistry; Sulfide; Atom (system on chip); Computational chemistry; Stereochemistry; Organic chemistry; Computer science; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001934347,0.0004528851,0.00009848444,0.0001677757,0.0001202971,0.0003394861,0.000220302,0.0002679218,0.001898887],"category_scores_gemma":[0.0001585917,0.0001312609,0.0001724033,0.0001611346,0.0002495821,0.0003627111,0.0003455705,0.0005270211,0.0006278639],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001842833,"about_ca_system_score_gemma":0.0002265141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002358872,"about_ca_topic_score_gemma":0.0003770059,"domain_scores_codex":[0.9999393,0.00001029335,0.000003853394,0.00001443858,0.00001301629,0.00001910023],"domain_scores_gemma":[0.999925,0.0000211512,0.00001623451,0.0000124207,0.00001319718,0.00001194982],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001226425,0.00006401119,0.0002900269,0.0002665045,0.00001608665,0.0006056861,0.0001007535,0.001305843,0.9438696,0.01515016,0.0007766135,0.0374321],"study_design_scores_gemma":[0.00001459758,0.0006814447,0.0005321972,0.00001464907,0.00001725545,0.0005325562,0.00002685038,0.002138845,0.9734817,0.001112715,0.02143125,0.0000159865],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8897415,0.009506349,0.058262,0.0006742995,0.0003577778,0.0001261684,0.0004490471,0.0004591973,0.04042352],"genre_scores_gemma":[0.9816657,0.003957442,0.01001487,0.0000931488,0.00004299242,0.00003844774,0.0002017021,0.00003071756,0.003955091],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001898887,"threshold_uncertainty_score":0.006352425,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008568320423231883,"score_gpt":0.2373742782907123,"score_spread":0.2288059578674804,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}