{"id":"W4283032836","doi":"10.3390/inorganics10060084","title":"Molecular Structures and Redox Properties of Homoleptic Aluminum(III) Complexes with Azobisphenolate (azp) Ligands","year":2022,"lang":"en","type":"article","venue":"Inorganics","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; Brock University","keywords":"Homoleptic; Chemistry; Redox; Ligand (biochemistry); Crystallography; Inorganic chemistry; Cyclic voltammetry; Photochemistry; Electrochemistry; Organic chemistry; Physical chemistry; Metal","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001546981,0.0001960404,0.0004547109,0.0000875937,0.0001876915,0.00002607598,0.0001535172,0.0000383796,0.0002431064],"category_scores_gemma":[0.00003881703,0.0001353104,0.00005398842,0.0002074976,0.0001895319,0.00005151664,0.0002189292,0.0002295111,0.000001893971],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003218009,"about_ca_system_score_gemma":0.0001042687,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000121185,"about_ca_topic_score_gemma":0.00001167875,"domain_scores_codex":[0.9987484,0.00005971859,0.0003007348,0.0002631873,0.0004122193,0.0002157684],"domain_scores_gemma":[0.9993067,0.00001706108,0.0001250841,0.0003691426,0.00009766601,0.0000842986],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004767613,0.00006406722,0.001307073,0.0001884124,0.0001507378,0.00002764945,0.001530569,0.00004696936,0.99453,0.00100438,0.0001112286,0.0005621336],"study_design_scores_gemma":[0.001034634,0.00148114,0.002517944,0.00009837392,0.000241594,0.0004784563,0.001630654,0.0003662038,0.9891662,0.000430378,0.002297698,0.0002567436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936251,0.005001888,0.00003163729,0.0002722143,0.00005265221,0.0003147508,0.00001324827,0.00004609987,0.0006424178],"genre_scores_gemma":[0.9986702,0.00004735383,0.000519873,0.0003353354,0.00002649733,0.00001994623,0.000008249626,0.00004506334,0.0003274965],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005363837,"threshold_uncertainty_score":0.5517799,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01998958140777677,"score_gpt":0.215249673040105,"score_spread":0.1952600916323282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}