{"id":"W4283170385","doi":"10.1002/anie.202206637","title":"Highly Active and Thermally Robust Nickel Enolate Catalysts for the Synthesis of Ethylene‐Acrylate Copolymers","year":2022,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dow Chemical (Canada)","funders":"Dow Chemical Company","keywords":"Copolymer; Ethylene; Steric effects; Catalysis; Nickel; Polymer chemistry; Phosphine; Materials science; Acrylate; Ligand (biochemistry); Thermal stability; Methyl acrylate; Chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001827098,0.0001574839,0.0002048461,0.00007412435,0.0002600008,0.00003255359,0.0003925212,0.00005290629,0.005379615],"category_scores_gemma":[0.0001444343,0.0001340731,0.0001798275,0.0001072131,0.0001116834,0.0001432572,0.0001893032,0.000145605,0.000002666027],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001378813,"about_ca_system_score_gemma":0.00004851466,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001530416,"about_ca_topic_score_gemma":0.00001676601,"domain_scores_codex":[0.9988578,0.00001483924,0.0002832059,0.00029012,0.0003940357,0.0001599974],"domain_scores_gemma":[0.9985937,0.000721719,0.0002828651,0.0002387904,0.0001197789,0.00004314202],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002968104,0.0001563031,0.00006637649,0.0000680167,0.0009596908,0.000002513681,0.0005709562,0.0001163331,0.9648896,0.0004669259,0.001639707,0.03076678],"study_design_scores_gemma":[0.0003302472,0.00001493025,0.0002655973,0.00001964382,0.0002026936,0.00001202169,0.001135751,0.0002906747,0.9807526,0.0002206806,0.01660521,0.0001499852],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9333338,0.001861485,0.00142341,0.008281643,0.001443533,0.0004569158,0.006790218,0.0001436577,0.04626533],"genre_scores_gemma":[0.9967479,0.0001773707,0.00007086599,0.00008487361,0.0003825511,0.0003494485,0.0004386673,0.0000277073,0.001720581],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06341413,"threshold_uncertainty_score":0.9955296,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01602106133266555,"score_gpt":0.2303359449793788,"score_spread":0.2143148836467133,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}