{"id":"W4283259739","doi":"10.1002/chem.202200637","title":"A High‐Nuclear Isopolymolybdate Cluster Assembled with an Anionic [{Mo<sub>24</sub>O<sub>48</sub>(OMe)<sub>32</sub>}]<sup>8−</sup> and Two Charge‐Neutral [{Mo<sub>24</sub>O<sub>52</sub>(OMe)<sub>28</sub>}] Cages","year":2022,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"National Natural Science Foundation of China","keywords":"Cluster (spacecraft); Charge (physics); Charge exchange; Atomic physics; Physics; Chemistry; Crystallography; Ion; Computer science; Operating system","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004237686,0.0001825543,0.0001582822,0.0001012385,0.0001698044,0.0001640285,0.0002550383,0.0001797818,0.001079748],"category_scores_gemma":[0.00008294355,0.0001159912,0.00008510399,0.00009493272,0.0001722103,0.0001407146,0.0002178718,0.0001829591,0.0002107233],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003133457,"about_ca_system_score_gemma":0.0001560901,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008536438,"about_ca_topic_score_gemma":0.001321214,"domain_scores_codex":[0.999958,0.00000352103,0.000001822507,0.00001337318,0.0000118181,0.00001149269],"domain_scores_gemma":[0.9999452,0.000005065191,0.00001190217,0.000006727307,0.000007722329,0.00002340165],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000717252,0.000009411835,0.0001492288,0.00003116122,0.000003378696,0.000028427,0.00001835989,0.0002056044,0.9983925,0.0001460523,0.00004351723,0.0009005494],"study_design_scores_gemma":[0.00001416876,0.0001800603,0.001665385,0.000003107756,0.000009803897,0.00004564764,0.00001917064,0.00117199,0.9950547,0.0000306223,0.001798915,0.000006386628],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969174,0.00008774077,0.001963204,0.00002115238,0.000009877371,0.00001314603,0.00006133389,0.00005429172,0.0008718566],"genre_scores_gemma":[0.9945461,0.00005677982,0.003634383,0.00001074482,0.000002658328,0.00001812155,0.000115347,0.00002352822,0.001592384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001079748,"threshold_uncertainty_score":0.003612101,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01176444384799808,"score_gpt":0.2120082295839955,"score_spread":0.2002437857359974,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}