{"id":"W4283370351","doi":"10.1021/jacs.2c02972","title":"Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO <sub>2</sub> Reduction Catalyzed by Iron Porphyrins","year":2022,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Canadian Institute for Advanced Research; Stanford University; Lawrence Berkeley National Laboratory; National Science Foundation","keywords":"Chemistry; Bicarbonate; Catalysis; Porphyrin; Electrochemistry; Inorganic chemistry; Electrolyte; Coordination sphere; Electrocatalyst; Combinatorial chemistry; Photochemistry; Metal; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008707208,0.0002210968,0.0001912563,0.00009095907,0.00008525467,0.0002217891,0.0001897782,0.0001867056,0.0009534254],"category_scores_gemma":[0.000212638,0.0001116284,0.00008237217,0.0001060477,0.0002088616,0.0002028631,0.0002258016,0.0003117461,0.0002041901],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002026358,"about_ca_system_score_gemma":0.0001302937,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004399612,"about_ca_topic_score_gemma":0.0008189229,"domain_scores_codex":[0.999926,0.000007117183,0.00000352545,0.00001900864,0.0000241691,0.00002017333],"domain_scores_gemma":[0.9999421,0.00001514552,0.0000148812,0.000004565647,0.000009546705,0.00001383012],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006028014,0.00001305452,0.0000822503,0.00003169351,0.0000023658,0.00002391528,0.00001541111,0.0001255498,0.9975399,0.00008615664,0.0000454553,0.001973869],"study_design_scores_gemma":[0.000003864752,0.00006293775,0.0004293431,0.000001283642,0.000001707652,0.00002836616,0.000005139385,0.0005856123,0.9984205,0.000009353845,0.000450493,0.000001567648],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956448,0.0004156257,0.002166553,0.00005451012,0.00001367566,0.00001214808,0.00004794946,0.00009318502,0.001551661],"genre_scores_gemma":[0.9966596,0.0002623595,0.002169749,0.00002652589,0.000005000173,0.00001118686,0.00003349527,0.00002033258,0.0008116933],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009534254,"threshold_uncertainty_score":0.003189564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005468105666179912,"score_gpt":0.2327758319103744,"score_spread":0.2273077262441945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}