{"id":"W4283370351","doi":"10.1021/jacs.2c02972","title":"Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO <sub>2</sub> Reduction Catalyzed by Iron Porphyrins","year":2022,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Canadian Institute for Advanced Research; Stanford University; Lawrence Berkeley National Laboratory; National Science Foundation","keywords":"Chemistry; Bicarbonate; Catalysis; Porphyrin; Electrochemistry; Inorganic chemistry; Electrolyte; Coordination sphere; Electrocatalyst; Combinatorial chemistry; Photochemistry; Metal; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000566351,0.0001532569,0.0002837708,0.00002469637,0.0002196916,0.00003202483,0.0005445562,0.00004916326,0.00008313952],"category_scores_gemma":[0.00006349714,0.0001061218,0.0004025439,0.0007464461,0.0002311791,0.0001109341,0.0001074183,0.0009549226,6.88683e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000536664,"about_ca_system_score_gemma":0.0000745279,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001481776,"about_ca_topic_score_gemma":0.000006174002,"domain_scores_codex":[0.9983417,0.0001664395,0.0004835496,0.0001945931,0.0005598807,0.0002538429],"domain_scores_gemma":[0.9986484,0.0001264983,0.0008963454,0.0002166777,0.00006244556,0.0000496183],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005986217,0.0001120578,0.0000522039,0.000008289564,0.00003703061,7.906051e-7,0.0004808808,0.00003750386,0.9786814,0.00002183872,0.01651332,0.003994798],"study_design_scores_gemma":[0.0002703003,0.00007462916,0.00007018463,0.000008996069,0.00002936228,0.0002247281,0.002706882,0.000122377,0.9891813,0.0005226986,0.006657698,0.0001308571],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968648,0.0001398536,0.00009161466,0.002441593,0.00009007535,0.0001052641,0.00001107806,0.00002488014,0.000230825],"genre_scores_gemma":[0.9990009,0.00005162122,0.000207585,0.0003808903,0.00023828,0.00002819648,0.00002343837,0.00001986302,0.00004923024],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01049987,"threshold_uncertainty_score":0.4327521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005468105666179912,"score_gpt":0.2327758319103744,"score_spread":0.2273077262441945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}