{"id":"W4283398271","doi":"10.1002/ejoc.202200570","title":"Rapid and Mild Cleavage of Aryl‐Alkyl Ethers to Liberate Phenols","year":2022,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Aryl; Alkyl; Isopropyl; Silylation; Ether cleavage; Steric effects; Borane; Phenols; Organic chemistry; Medicinal chemistry; Ether; Cleavage (geology); Tris; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000640489,0.0001865744,0.0003021617,0.0000439611,0.0001606,0.00005138172,0.0004858086,0.00002904299,0.005447475],"category_scores_gemma":[0.0002096499,0.0002014578,0.000134501,0.0002303761,0.00009608654,0.00006864913,0.0003535505,0.0007137523,0.00001851108],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001487601,"about_ca_system_score_gemma":0.0001303152,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001802803,"about_ca_topic_score_gemma":2.01155e-7,"domain_scores_codex":[0.9985173,0.000004716771,0.0006466209,0.0002330679,0.0003751327,0.0002231703],"domain_scores_gemma":[0.9986249,0.00009398916,0.0005365892,0.0004064457,0.0001035891,0.0002344558],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001098771,0.0001051184,0.0001552835,0.00009503543,0.0001014639,0.0001713445,0.0010035,0.000058473,0.9917019,7.745169e-7,0.004292849,0.002204358],"study_design_scores_gemma":[0.001013428,0.00005695219,0.0002600733,0.00007547166,0.00007186616,0.00107532,0.001601425,0.00001050632,0.9754524,0.00000987359,0.02017668,0.0001960429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903893,0.0006893456,0.00001643521,0.0003823286,0.0001215303,0.00003029227,0.00004695337,0.00002875218,0.008295001],"genre_scores_gemma":[0.9969819,0.00006356185,0.00007322875,0.00009191175,0.0003168854,7.89965e-7,0.000008847378,0.0000816847,0.00238125],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01624956,"threshold_uncertainty_score":0.9954617,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01456214113130453,"score_gpt":0.2241913310278915,"score_spread":0.209629189896587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}