{"id":"W4283398271","doi":"10.1002/ejoc.202200570","title":"Rapid and Mild Cleavage of Aryl‐Alkyl Ethers to Liberate Phenols","year":2022,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Aryl; Alkyl; Isopropyl; Silylation; Ether cleavage; Steric effects; Borane; Phenols; Organic chemistry; Medicinal chemistry; Ether; Cleavage (geology); Tris; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004268324,0.0007215484,0.0001839346,0.0002298509,0.0001580495,0.0002004512,0.0002951228,0.0002174289,0.002353479],"category_scores_gemma":[0.000287935,0.0002039961,0.0001999814,0.0001794617,0.0002061933,0.0003608917,0.0003171364,0.0006019291,0.001273872],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001498875,"about_ca_system_score_gemma":0.0004176855,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005314658,"about_ca_topic_score_gemma":0.001211608,"domain_scores_codex":[0.9997283,0.00003236851,0.00002293031,0.00004627016,0.00008041134,0.00008974718],"domain_scores_gemma":[0.9998541,0.00002877482,0.00003815736,0.00002460074,0.00002840001,0.00002600511],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004042784,0.00002057989,0.00007063312,0.00008034363,0.000008479746,0.0001092555,0.00002836752,0.00010501,0.9944686,0.0001532227,0.0001301395,0.004784938],"study_design_scores_gemma":[0.000006593751,0.0001040377,0.0003586554,0.000003968379,0.000006523915,0.0001350078,0.000009753904,0.0001298419,0.9947002,0.0000393665,0.00450086,0.000005192165],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8836609,0.008153943,0.08922061,0.0003891726,0.0001428245,0.0002745706,0.00115379,0.0004963763,0.01650768],"genre_scores_gemma":[0.9619254,0.004733376,0.02435,0.0001141217,0.00002968492,0.00007895507,0.001220008,0.0001294525,0.007418968],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002353479,"threshold_uncertainty_score":0.007873178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01456214113130453,"score_gpt":0.2241913310278915,"score_spread":0.209629189896587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}