{"id":"W4283815183","doi":"10.1016/j.jhazmat.2022.129514","title":"Role of persistent free radicals and lewis acid sites in visible-light-driven wet peroxide activation by solid acid biochar catalysts – A mechanistic study","year":2022,"lang":"en","type":"article","venue":"Journal of Hazardous Materials","topic":"Advanced oxidation water treatment","field":"Environmental Science","cited_by":27,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Radical; Biochar; Electron paramagnetic resonance; Catalysis; Photochemistry; Pyrolysis; Photocatalysis; Adsorption; Peroxide; Lewis acids and bases; Hydrogen peroxide; Inorganic chemistry; Nuclear chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005823144,0.0001827213,0.000465784,0.0001475591,0.0001393877,0.00004470824,0.0003217822,0.00003656945,0.001101095],"category_scores_gemma":[0.0000692374,0.0001549127,0.00008282162,0.0001467876,0.00005039178,0.0003100216,0.0003883449,0.00009884762,0.00001243284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004703751,"about_ca_system_score_gemma":0.00002124772,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000125358,"about_ca_topic_score_gemma":0.0000234268,"domain_scores_codex":[0.9979229,0.0002754392,0.0007177843,0.0002496,0.0006168291,0.0002174335],"domain_scores_gemma":[0.9989149,0.000031862,0.0006855213,0.0002452187,0.00002159495,0.0001009207],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002168459,0.0006118902,0.002196621,0.00001099613,0.0000937609,0.00002739384,0.001963157,0.0009358767,0.9934178,0.000004128889,0.0002918926,0.0002296474],"study_design_scores_gemma":[0.001589769,0.001257086,0.002732849,0.00002239673,0.00009187704,0.00008819171,0.00258365,0.00002825444,0.9908704,0.0003575871,0.0002299515,0.000147968],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986694,0.0001987778,0.00007532792,0.0004140922,0.00008762193,0.0004133102,0.0001108579,0.000008883992,0.00002174258],"genre_scores_gemma":[0.9989381,0.00002843514,0.000850014,0.00004151778,0.00002564549,0.00003577826,0.0000209714,0.00002023543,0.00003924657],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00254737,"threshold_uncertainty_score":0.999812,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008055516695023664,"score_gpt":0.2306604402575542,"score_spread":0.2226049235625305,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}