{"id":"W4283822222","doi":"10.1002/chem.202201983","title":"Cover Feature: Radical Complexes of Nickel(II)/Copper(II) and Redox Non‐innocent MB‐DIPY Ligands: Unusual Stability and Strong Near‐Infrared Absorption at <i>λ</i><sub>max</sub> ∼1300 nm (Chem. Eur. J. 41/2022)","year":2022,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Radical; Nickel; Chromophore; Chemistry; Copper; Redox; Absorption (acoustics); Photochemistry; Ion; Absorption spectroscopy; Radical ion; Inorganic chemistry; Materials science; Organic chemistry; Physics; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004979548,0.0004505908,0.0002977588,0.0003391381,0.0003453816,0.0003441438,0.0006689357,0.0005589768,0.1348222],"category_scores_gemma":[0.00009215791,0.0001423148,0.0001275426,0.0003728665,0.0002390952,0.0003976531,0.0003598461,0.0003295106,0.01913971],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003178923,"about_ca_system_score_gemma":0.00009355915,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002475931,"about_ca_topic_score_gemma":0.0004835342,"domain_scores_codex":[0.9999477,0.000001668721,0.000001718153,0.00001460057,0.00002333503,0.00001102607],"domain_scores_gemma":[0.9999549,0.000009990582,0.000007161933,0.000003381484,0.000005014586,0.0000195347],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009133396,0.0001308318,0.0006009123,0.001404109,0.00002517065,0.0007534613,0.00006475484,0.0003194145,0.4809333,0.006798789,0.34527,0.1627859],"study_design_scores_gemma":[0.0001549779,0.0006134203,0.01101006,0.00009869088,0.00002865467,0.001680771,0.00006249634,0.001807529,0.2499278,0.001308587,0.733284,0.00002303282],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1525601,0.02172533,0.0053772,0.005678623,0.005859598,0.0002358015,0.004731803,0.003469787,0.8003616],"genre_scores_gemma":[0.4532199,0.009589611,0.003573996,0.001567777,0.003070968,0.0001529256,0.004571406,0.000524305,0.5237291],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.1348222,"threshold_uncertainty_score":0.4510253,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01427388275238925,"score_gpt":0.2230151616668006,"score_spread":0.2087412789144113,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}