{"id":"W4284672167","doi":"10.3389/fchem.2022.949355","title":"Vanillin: A Promising Biosourced Building Block for the Preparation of Various Heterocycles","year":2022,"lang":"en","type":"review","venue":"Frontiers in Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Cegep de Thetford","funders":"Fonds de recherche du Québec – Nature et technologies","keywords":"Vanillin; Moiety; Chemistry; Depolymerization; Organic chemistry; Lignin; Green chemistry; Aldehyde; Combinatorial chemistry; Supramolecular chemistry; Catalysis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002946002,0.0005950336,0.001441299,0.00006249021,0.0002533657,0.00005466816,0.0009702889,0.0005449275,0.0005351988],"category_scores_gemma":[0.0004921612,0.0005299909,0.0006930325,0.0003918241,0.0001623076,0.00004781302,0.0002668216,0.0009610539,7.92485e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001055819,"about_ca_system_score_gemma":0.0004143299,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009058454,"about_ca_topic_score_gemma":9.519651e-7,"domain_scores_codex":[0.9972753,0.00003218876,0.001087689,0.0008079597,0.0003611197,0.0004357212],"domain_scores_gemma":[0.9970208,0.0006888162,0.001147163,0.001012218,0.00005190731,0.00007902846],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001742855,0.0006158828,0.00005029756,0.1457457,0.002440243,0.00002034941,0.0006124347,0.0002917946,0.1832006,0.000004913764,0.007992038,0.6588514],"study_design_scores_gemma":[0.0004064385,0.000007395176,9.178211e-8,0.002678768,0.0008099586,0.00007988225,0.0003264573,0.0003877099,0.09234747,0.00003782091,0.9024287,0.0004893473],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0005523399,0.9941716,0.0006956901,0.00001907072,0.0003432485,0.000690226,0.0004358986,0.00009967387,0.002992247],"genre_scores_gemma":[0.0006766796,0.9898207,0.004226773,0.000004924565,0.0005164738,0.001100881,0.0004808087,0.0001959692,0.002976805],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8944366,"threshold_uncertainty_score":0.9997151,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03630138018618068,"score_gpt":0.3236442386767536,"score_spread":0.2873428584905729,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}