{"id":"W4285018376","doi":"10.1021/acs.organomet.2c00113","title":"Osmium(II)-Induced Rearrangement of Allenols for Metallafuran Complexes","year":2022,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Research Grants Council, University Grants Committee","keywords":"Chemistry; Allene; Osmium; Deprotonation; Protonation; Alkene; Rearrangement reaction; Medicinal chemistry; Hydride; Cope rearrangement; Stereochemistry; Metal; Photochemistry; Ion; Ruthenium; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009059232,0.0002614589,0.0001810683,0.0001022713,0.0001266659,0.0002332266,0.000314527,0.000178151,0.001569826],"category_scores_gemma":[0.0001341777,0.000125634,0.0001376275,0.000125163,0.0001459288,0.0001456103,0.0002117208,0.0002636885,0.0002025711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003199104,"about_ca_system_score_gemma":0.0001302002,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007038544,"about_ca_topic_score_gemma":0.001459746,"domain_scores_codex":[0.9999366,0.000008312337,0.000004918889,0.00001373899,0.00001289331,0.00002365319],"domain_scores_gemma":[0.9999658,0.000005484281,0.00001051679,0.00000478129,0.000004776664,0.000008658813],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002860678,0.00003209904,0.0002435623,0.0001704129,0.00001935354,0.0001279866,0.0001346421,0.0006823135,0.9942006,0.001459541,0.0002660989,0.002377412],"study_design_scores_gemma":[0.00006493823,0.0004503697,0.0009904781,0.000009708865,0.00001589666,0.0001451436,0.00005719914,0.001672112,0.9924685,0.0001011268,0.004008855,0.00001567111],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956353,0.0002467207,0.0008620412,0.00003642248,0.00001159498,0.00001818225,0.00008668652,0.00003871732,0.003064294],"genre_scores_gemma":[0.9984214,0.0001705912,0.000547894,0.0000110876,0.000002292549,0.000008335651,0.00008851141,0.000009013968,0.000740856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001569826,"threshold_uncertainty_score":0.005251646,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04019053675943476,"score_gpt":0.2663881795472946,"score_spread":0.2261976427878598,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}