{"id":"W4285039720","doi":"10.2533/chimia.2000.96","title":"Photochemistry of Hydrocarbon Radicals","year":2000,"lang":"en","type":"article","venue":"CHIMIA International Journal for Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"Rheinische Friedrich-Wilhelms-Universität Bonn","keywords":"Radical; Photochemistry; Chemistry; Hydrocarbon; Propargyl; Photoionization; Reaction dynamics; Picosecond; Combustion; Chemical reaction; Nanosecond; Spectroscopy; Radical disproportionation; Hydrogen atom abstraction; Organic chemistry; Molecule; Laser; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000131391,0.0001500257,0.00008033169,0.0002162651,0.000216236,0.0001687498,0.0001471244,0.0002440105,0.001733566],"category_scores_gemma":[0.000219377,0.00006537623,0.0001092147,0.0001776904,0.0002360183,0.0003335515,0.0001644031,0.0003516028,0.0002374468],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002304551,"about_ca_system_score_gemma":0.0001096221,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004548836,"about_ca_topic_score_gemma":0.0004630041,"domain_scores_codex":[0.9999238,0.000008796403,0.000001679635,0.0000180373,0.00002579922,0.00002187126],"domain_scores_gemma":[0.9998881,0.00005199693,0.00002636778,0.00001233458,0.00001277816,0.000008554871],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007088409,0.00001823209,0.0007217872,0.0001047894,0.000007884704,0.00006639634,0.00007220967,0.0007240284,0.9865639,0.002815758,0.0001690077,0.008665143],"study_design_scores_gemma":[0.000007464536,0.0002109354,0.003801856,0.000006483582,0.000008010477,0.0001828517,0.00003402867,0.001731647,0.9890325,0.0007194101,0.00425663,0.000008114052],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9767159,0.008472765,0.007480884,0.0001371973,0.00003593149,0.00001788621,0.0001762051,0.00007572116,0.006887498],"genre_scores_gemma":[0.9951895,0.001525699,0.001232446,0.00002794581,0.00001132081,0.000007578496,0.00008848561,0.000007310332,0.001909813],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001733566,"threshold_uncertainty_score":0.005799353,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009718676608894536,"score_gpt":0.2839672342149003,"score_spread":0.2742485576060057,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}