{"id":"W4285039720","doi":"10.2533/chimia.2000.96","title":"Photochemistry of Hydrocarbon Radicals","year":2000,"lang":"en","type":"article","venue":"CHIMIA International Journal for Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"Rheinische Friedrich-Wilhelms-Universität Bonn","keywords":"Radical; Photochemistry; Chemistry; Hydrocarbon; Propargyl; Photoionization; Reaction dynamics; Picosecond; Combustion; Chemical reaction; Nanosecond; Spectroscopy; Radical disproportionation; Hydrogen atom abstraction; Organic chemistry; Molecule; Laser; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001429039,0.0002520957,0.0003125943,0.00003070678,0.0001001055,0.00007057624,0.001013614,0.0002890964,0.0231493],"category_scores_gemma":[0.0004785121,0.0002490819,0.0004921823,0.00007241169,0.000208892,0.000125353,0.00004308011,0.0006181496,0.00002028968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002554749,"about_ca_system_score_gemma":0.0001576573,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008044214,"about_ca_topic_score_gemma":1.502478e-7,"domain_scores_codex":[0.9978839,0.000004935389,0.0007468075,0.000324254,0.0007010355,0.0003390872],"domain_scores_gemma":[0.9985639,0.0002191885,0.0003164899,0.0003081259,0.0002409615,0.0003513708],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002818799,0.0002340954,0.000109036,0.00009853659,0.000249637,0.00001794732,0.00002724102,0.00004540591,0.9880784,0.00001659126,0.004107152,0.006734065],"study_design_scores_gemma":[0.001301697,0.000008929875,0.0000148251,0.0001730483,0.00004466627,0.0005273304,0.00003385022,0.0005709606,0.9121221,0.001870423,0.08310451,0.0002276225],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8792066,0.0001534332,0.00009501088,0.0003498827,0.0002461411,0.00007455968,0.0001600534,0.0000647321,0.1196496],"genre_scores_gemma":[0.9858041,0.0002115518,0.0008551453,0.0001077663,0.001610204,0.00006712272,0.0001650802,0.00005153568,0.01112751],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1085221,"threshold_uncertainty_score":0.9999961,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009718676608894536,"score_gpt":0.2839672342149003,"score_spread":0.2742485576060057,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}