{"id":"W4285093328","doi":"10.1021/acs.inorgchem.2c01427","title":"Chain Length Effect on the Structural and Emission Properties of the CuI/Bis((4-methoxyphenyl)thio)alkane Coordination Polymers","year":2022,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Centre National de la Recherche Scientifique; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Cubane; Crystallography; Ribbon; Luminescence; SBus; Quantum yield; Polymer; Cluster (spacecraft); Ligand (biochemistry); Dodecahedron; Stereochemistry; Crystal structure; Fluorescence; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001867779,0.0003703155,0.0001208222,0.0001495518,0.0001051682,0.0002022409,0.0001632191,0.0001570286,0.001148731],"category_scores_gemma":[0.0004485629,0.0001540214,0.0001134928,0.0002166196,0.0001537088,0.0001967553,0.0001614286,0.0002932048,0.0002097695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002482715,"about_ca_system_score_gemma":0.0001824325,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007420088,"about_ca_topic_score_gemma":0.001103144,"domain_scores_codex":[0.9999024,0.00001743524,0.000009298145,0.00002455044,0.0000156466,0.00003071068],"domain_scores_gemma":[0.9997186,0.00008856938,0.00007969925,0.00002702682,0.00004395903,0.00004202656],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002466688,0.00002405785,0.0003208117,0.00005361409,0.000007113468,0.00004560591,0.000055796,0.0004356358,0.9962845,0.000100628,0.00003007968,0.002395446],"study_design_scores_gemma":[0.000008761425,0.0002623802,0.002800057,0.000006902797,0.00001166219,0.00002410172,0.00001485646,0.0008508755,0.9954359,0.00001860947,0.0005591426,0.000006778018],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985568,0.0001963111,0.000240807,0.00001319515,0.000002634971,0.000004847342,0.00006564677,0.00002349535,0.0008963171],"genre_scores_gemma":[0.99852,0.0002375347,0.0004731624,0.0000121043,0.000002225169,0.00001808369,0.00009843994,0.00001974421,0.0006187484],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001148731,"threshold_uncertainty_score":0.00384289,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01004981234589933,"score_gpt":0.2130443551706256,"score_spread":0.2029945428247262,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}