{"id":"W4285236859","doi":"10.1039/d2py00470d","title":"Donor modification of thermally activated delayed fluorescence photosensitizers for organocatalyzed atom transfer radical polymerization","year":2022,"lang":"en","type":"article","venue":"Polymer Chemistry","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Photochemistry; Chemistry; Atom-transfer radical-polymerization; Polymerization; Acceptor; Fluorescence; Radical polymerization; Chain transfer; Polymer chemistry; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008342384,0.0002837149,0.0003354255,0.00004206848,0.0002804181,0.00002017217,0.0003616554,0.0001450157,0.002536117],"category_scores_gemma":[0.00002553559,0.0003204352,0.0001757598,0.0002721068,0.0001325883,0.0001423503,0.00006008065,0.0002087715,0.000001807202],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001031794,"about_ca_system_score_gemma":0.0001501744,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003440667,"about_ca_topic_score_gemma":2.705605e-7,"domain_scores_codex":[0.9982007,0.00002924087,0.0005465177,0.0004938638,0.0003773454,0.0003523895],"domain_scores_gemma":[0.9989784,0.0001058767,0.0002421575,0.0004789421,0.00007275472,0.0001218607],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007621695,0.0002154131,0.00008869332,0.0001599954,0.000103081,0.000001640583,0.0003814089,0.00002941486,0.9911666,0.00006877312,0.00001731212,0.007005499],"study_design_scores_gemma":[0.001077836,0.0000167492,0.0000284785,0.00002268824,0.00009132936,0.00001769144,0.0003682718,0.001156359,0.9961989,0.00001213859,0.0006720175,0.0003375303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9890791,0.000394463,0.008436563,0.0002086226,0.00007691634,0.0001766132,0.0007683895,0.0001410267,0.0007182728],"genre_scores_gemma":[0.9962505,0.00002995438,0.0001838087,0.00007117323,0.0001176943,0.000254807,0.002154152,0.00008374452,0.0008542397],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008252755,"threshold_uncertainty_score":0.9999248,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01051243587119586,"score_gpt":0.2232422535287958,"score_spread":0.2127298176576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}