{"id":"W4285464460","doi":"10.1002/cjce.24145","title":"Emulsion polymerization of vinylidene fluoride: Effects of mixing and reaction conditions on the initial rate of polymerization","year":2021,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Innovative Microfluidic and Catalytic Techniques Innovation","field":"Engineering","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Agence Nationale de la Recherche","keywords":"Polymerization; Emulsion polymerization; Nucleation; Materials science; Precipitation polymerization; Chain transfer; Chemical engineering; Polymer chemistry; Reaction rate; Coagulation; Bulk polymerization; Mixing (physics); Fluoride; Chemistry; Radical polymerization; Polymer; Organic chemistry; Catalysis; Composite material; Inorganic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001133879,0.0005596077,0.0005427907,0.0003423998,0.0002280924,0.0005351214,0.0003084519,0.0004970718,0.001191683],"category_scores_gemma":[0.002306265,0.0002536127,0.0002830442,0.000322415,0.0002520764,0.0007028587,0.0002135817,0.000707701,0.0002692059],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003878997,"about_ca_system_score_gemma":0.0004202041,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00139745,"about_ca_topic_score_gemma":0.0009905093,"domain_scores_codex":[0.9995821,0.00009240452,0.00004691581,0.00008596497,0.00008916022,0.0001034616],"domain_scores_gemma":[0.9986261,0.0008687266,0.0002205482,0.00004414714,0.00014252,0.0000979293],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004845141,0.00009753235,0.000218441,0.0000722272,0.000008817613,0.00005745208,0.00004223507,0.0001596209,0.9967194,0.00004176723,0.00002342862,0.002074537],"study_design_scores_gemma":[0.00002310689,0.0004528423,0.0007474389,0.000007358758,0.00001359717,0.00003841949,0.00001173147,0.0009894326,0.9974112,0.00001399233,0.0002804542,0.00001053609],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934843,0.001855539,0.003357502,0.00005967619,0.0000447131,0.00005596172,0.0001303038,0.00006588835,0.0009460447],"genre_scores_gemma":[0.9950286,0.0008143319,0.003438947,0.00002029501,0.00001727915,0.00002459441,0.0000965715,0.00003618176,0.000523176],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00139745,"threshold_uncertainty_score":0.005996585,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007334430434822591,"score_gpt":0.2098324497735342,"score_spread":0.2024980193387116,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}