{"id":"W4285794603","doi":"10.26434/chemrxiv-2022-w2th1","title":"A Monoboranyl Analogue of 1,2-bis(di-tert-butylphosphino)ethane","year":2022,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; Council of Ontario Universities; University of Windsor","keywords":"Diphosphines; Moiety; Chemistry; Ligand (biochemistry); Boron; Lewis acids and bases; Nickel; Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008722815,0.0002697558,0.0001413264,0.000125975,0.0001609356,0.0002364693,0.0002518066,0.0002256929,0.00324263],"category_scores_gemma":[0.0001031691,0.0001186189,0.00008094108,0.000137668,0.0001640717,0.0002859271,0.0002885124,0.000365445,0.0007350108],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002332635,"about_ca_system_score_gemma":0.0001846576,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003328631,"about_ca_topic_score_gemma":0.0008646103,"domain_scores_codex":[0.9999222,0.00001409403,0.000005942678,0.00002565652,0.00001362849,0.00001858507],"domain_scores_gemma":[0.9999496,0.000006991348,0.00001352034,0.000009596049,0.000004865086,0.00001546628],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001217054,0.0000188479,0.00009367464,0.0001939283,0.00000653297,0.0001250282,0.00004455861,0.0001560133,0.9936283,0.0009884493,0.0002117031,0.004411351],"study_design_scores_gemma":[0.00002249351,0.0003949354,0.000781868,0.000009849402,0.00001079122,0.0005427045,0.00002856367,0.000301671,0.9780368,0.0001391941,0.01972055,0.00001046208],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9490641,0.003847823,0.0129095,0.0002997895,0.0001314871,0.0001277704,0.0008207384,0.0002851691,0.03251366],"genre_scores_gemma":[0.9827388,0.001211843,0.008546336,0.0000812361,0.00001386384,0.00004312154,0.0003718049,0.00005373339,0.006939328],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00324263,"threshold_uncertainty_score":0.01084769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01682601082024969,"score_gpt":0.2496313031841524,"score_spread":0.2328052923639027,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}